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化驗
≥99.0% (GC)
形狀
liquid
品質
Arxada quality
製造商／商標名
Arxada AG
雜質
≤0.10% acid (as acetic acid)
≤0.10% water
≤0.5% ethyl acetoacetate
bp
95 °C/52 hPa (lit.)
密度
0.989 g/mL at 20 °C (lit.)
SMILES 字串
CC(C)OC(=O)CC(C)=O
InChI
1S/C7H12O3/c1-5(2)10-7(9)4-6(3)8/h5H,4H2,1-3H3
InChI 密鑰
GVIIRWAJDFKJMJ-UHFFFAOYSA-N
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應用
乙酰乙酸异丙酯可用作反应物，
- 在Ti（O-i-Pr）4存在下通过Knoevenagel反应合成：2-乙酰基-3-苯基-2-丙烯酸异丙酯。
- 通过与肉桂醛和伯胺反应取代1,4-二氢吡啶。
- 5-异丙氧羰基-6-甲基-4-苯基-3,4-二氢嘧啶-2（1H）-硫酮，通过与苯甲醛和硫脲的Biginelli反应。
Synthesis and biological evaluation of novel isopropyl 2-thiazolopyrimidine-6-carboxylate derivatives
Kotaiah Y, et al.
J. Korean Chem. Soc., 56(1), 68-73 (2012)
Organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-dicarbonyl compounds: straightforward access to enantiomerically enriched dihydropyridines
Jiang J, et al.
Angewandte Chemie (International Edition in English), 47(13), 2458-2462 (2008)
Novel Knoevenagel-type reaction via titanium enolate derived from Ti(Oi-Pr)4 and diketene
Hayashi M, et al.
Tetrahedron, 60(32), 6777-6783 (2004)
M M V Ramana et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 152, 165-171 (2015-07-25)
In the present work, isopropyl-6-amino-4-(3,5-bis(trifluoromethyl)phenyl)-5-cyano-2-methyl-4H-pyran-3-carboxylate (4H-pyran analog) has been synthesized by a three component reaction catalyzed by CsOH/γ-Al2O3 and characterized. The interaction of 4H-pyran analog with herring sperm DNA (hs DNA) under physiological conditions (phosphate buffer of pH 7.2) was
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