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670731

(S)-α,α-双(3,5-二甲苯基)-2-吡咯烷甲醇

Name: (<I>S</I>)-α,α-双(3,5-二甲苯基)-2-吡咯烷甲醇
Brand: ALDRICH

≥99% (HPLC)

别名:

(S)-(-)-2-[双(3,5-二甲苯基)羟甲基]吡咯烷

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About This Item

经验公式（希尔记法）:

C₂₁H₂₇NO

CAS号:

131180-63-7

分子量:

309.45

MDL號碼:

MFCD10566962

分類程式碼代碼:

12352005

PubChem物質ID:

329760383

NACRES:

NA.22

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(-)-DIP-Chloride^™

化驗

≥99% (HPLC)

光學純度

enantiomeric ratio: 97.5% (HPLC)

mp

98-101 °C

官能基

hydroxyl

儲存溫度

2-8°C

SMILES 字串

Cc1cc(C)cc(c1)C(O)([C@@H]2CCCN2)c3cc(C)cc(C)c3

InChI

1S/C21H27NO/c1-14-8-15(2)11-18(10-14)21(23,20-6-5-7-22-20)19-12-16(3)9-17(4)13-19/h8-13,20,22-23H,5-7H2,1-4H3/t20-/m0/s1

InChI 密鑰

MXIOBZPVLNQGIU-FQEVSTJZSA-N

應用

(S)-α,α-Bis(3,5-dimethylphenyl)-2-pyrrolidinemethanol can be used as:

A chiral organocatalyst in the preparation of α-[(phenyl)methyl]thio]alkanal derivatives using aldehydes as starting materials and [(phenyl)methyl]thio]triazole as a sulfur electrophile.
A catalyst in the preparation of chiral bipyrazolidin-3-one derivatives by cycloadditions of azomethine imines with α,β-unsaturated aldehydes.