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Merck

59760

Sigma-Aldrich

1-甲基咪唑鎓硫酸氢盐

95%

别名:

1-甲基咪唑硫酸氢盐

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About This Item

经验公式(希尔记法):
C4H6N2 · H2SO4
分子量:
180.18
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥94.5% (HPLC)
95%

形狀

solid

雜質

≤1% water

負離子痕跡

chloride (Cl-): ≤20 mg/kg

SMILES 字串

OS(O)(=O)=O.Cn1ccnc1

InChI

1S/C4H6N2.H2O4S/c1-6-3-2-5-4-6;1-5(2,3)4/h2-4H,1H3;(H2,1,2,3,4)

InChI 密鑰

TVEOIQKGZSIMNG-UHFFFAOYSA-N

應用

1-Methylimidazolium hydrogen sulfate is a Brønsted acidic ionic liquid that can be used:
  • As a component of a catalytic system along with chlorotrimethylsilane used in the preparation of 3,4-dihydropyrimidin-2(1H)-ones and hydroquinazoline-2,5-diones.
  • As a catalyst in the preparation of biologically important 2,5-dimethyl-N-substituted pyrroles.
  • As a reusable catalyst in the preparation of spiro[indoline-3′,2-quinazoline]2′,4(3H)-dione.
  • In the leaching of copper and zinc in brass dross using H2O2 as an oxidant.

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

>536.0 °F - (External MSDS)

閃點(°C)

> 280 °C - (External MSDS)

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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An environmental friendly approach for the synthesis of spiro [indoline-3′, 2-quinazoline] 2′, 4 (3H)-dione using 1-methylimidazolium hydrogen sulfate, as reusable catalyst
Kefayati H, et al.
J. Chin. Chem. Soc., 60(10), 1197-1201 (2013)

商品

Under the trade name BASIONICS™, BASF offers a portfolio of Ionic Liquids—mainly based on imidazolium cations. The BASIONICS™ portfolio opens up a broad range of basic properties of Ionic Liquids and is classified into standard, acidic, basic, liquid at RT and low viscosity products and opens up a wide range of possible applications.

Under the trade name BASIONICS™, BASF offers a portfolio of Ionic Liquids—mainly based on imidazolium cations. The BASIONICS™ portfolio opens up a broad range of basic properties of Ionic Liquids and is classified into standard, acidic, basic, liquid at RT and low viscosity products and opens up a wide range of possible applications.

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