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Merck
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579726

Sigma-Aldrich

Grubbs Catalyst® M102

Umicore, 97%

别名:

Grubbs Catalyst® M1a (C823), Grubbs Catalyst®第一代催化剂, 双(三环己基膦)亚苄基钌(IV)二氯化物, 苯基亚甲基双(三环己基磷)二氯化钌

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About This Item

经验公式（希尔记法）:
C43H72Cl2P2Ru
CAS号:
172222-30-9
分子量:
822.96
分類程式碼代碼:
12161600
PubChem物質ID:
24881009
NACRES:
NA.22

品質等級

100

化驗

97%

反應適用性

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

153 °C (dec.)

儲存溫度

2-8°C

SMILES 字串

C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]

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相关类别

應用

第一个被广泛用于有机合成的复分解催化剂。适用于各种反应条件下末端烯烃的无环二烯复分解聚合（ADMET）、应变环烯烃的开环复分解聚合（ROMP）、开环复分解（ROM）、烯烃交叉复分解（CM）和关环复分解（RCM）。

了解我们的复分解催化剂的更多信息。

其他說明

Aldrich用于烯烃复分解反应的Grubbs催化剂® 技术

法律資訊

Umicore 产品

有关更多信息，请访问http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

象形圖

Flame
GHS02

訊號詞

Warning

危險聲明

H228

危險分類

Flam. Sol. 2

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Dongwon Lee et al.
International journal of nanomedicine, 3(4), 471-476 (2008-01-01)
The overproduction of hydrogen peroxide is implicated in the progress of numerous life-threatening diseases and there is a great need for the development of contrast agents that can detect hydrogen peroxide in vivo. In this communication, we present a new
Brummer, O.; Ruckert, a.; Blechert, S.
Chemistry (Weinheim An Der Bergstrasse, Germany), 3, 441-441 (1997)
Young-Woo Kim et al.
Nature protocols, 6(6), 761-771 (2011-06-04)
This protocol provides a detailed procedure for the preparation of stapled α-helical peptides, which have proven their potential as useful molecular probes and as next-generation therapeutics. Two crucial features of this protocol are (i) the construction of peptide substrates containing
Schrodi, Y.; Pederson, R. L.
Aldrichimica Acta, 45-45 (2007)
T M Trnka et al.
Accounts of chemical research, 34(1), 18-29 (2001-02-15)
In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advances in catalyst design. State-of-the-art ruthenium catalysts are not only highly active but also
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