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品質等級
化驗
97%
形狀
solid
mp
48-52 °C (lit.)
SMILES 字串
Clc1ccc(CBr)cc1
InChI
1S/C7H6BrCl/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
InChI 密鑰
KQNBRMUBPRGXSL-UHFFFAOYSA-N
一般說明
4-Chlorobenzyl bromide undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid. It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide.
應用
4-Chlorobenzyl bromide may be used to synthesize 1-(4-chlorobenzyl)-2-(pyrrolidin-1-yl-methyl)-1H-benzimidazole dihydrochloride
包裝
4-Chlorobenzyl bromide may be used to synthesize:
- 1-[1-[2-[(4-chlorobenzyl)thio]phenyl]vinyl]-1H-imidazole
- 6-[4-(4-chlorobenzyl)piperazinyl]chromane
- N,N′-bis(4-chlorobenzyl)piperazine
- N-(4-chlorobenzyl)piperazine
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
6-(4-Benzylpiperazin-1-yl) benzodioxanes as selective ligands at cloned primate dopamine D 4 receptors.
Bioorganic & Medicinal Chemistry, 9(12), 3207-3213 (2001)
"Reduction of carbonyl compounds promoted by silicon hydrides under the influence of trimethylsilyl-based reagent"
Canadian Journal of Chemistry, 64(12), 2342-2347 (1986)
Royal Society of Chemistry Advances, 2(20), 7781- 7787 (2012)
Synthesis and antifungal activity of new 1-vinylimidazoles.
Journal of Medicinal Chemistry, 30(8), 1348-1354 (1987)
Synthesis of phenylacetic acids under rhodium-catalyzed carbonylation conditions.
Tetrahedron Letters, 41(40), 7601-7604 (2000)
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