418951

(DHQD)₂Pyr

97%

• 别名: 氢化奎尼定-2,5-二苯基-4,6-嘧啶二基二醚
• 经验公式（希尔记法）: C₅₆H₆₀N₆O₄
• CAS号: 149725-81-5
• 分子量: 881.11
• MDL號碼: MFCD00198108
• 分類程式碼代碼: 12352005
• PubChem物質ID: 24866252
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: 97%
• 光學活性: [α]20/D −390°, c = 1.2 in methanol
• mp: 247-250 °C (lit.)
• 官能基: phenyl
• SMILES 字串: CC[C@H]1CN2CCC1CC2[C@@H](Oc3nc(nc(O[C@H](C4CC5CCN4C[C@@H]5CC)c6ccnc7ccc(OC)cc67)c3-c8ccccc8)-c9ccccc9)c%10ccnc%11ccc(OC)cc%10%11
• InChI: 1S/C56H60N6O4/c1-5-35-33-61-27-23-39(35)29-49(61)52(43-21-25-57-47-19-17-41(63-3)31-45(43)47)65-55-51(37-13-9-7-10-14-37)56(60-54(59-55)38-15-11-8-12-16-38)66-53(50-30-40-24-28-62(50)34-36(40)6-2)44-22-26-58-48-20-18-42(64-4)32-46(44)48/h7-22,25-26,31-32,35-36,39-40,49-50,52-53H,5-6,23-24,27-30,33-34H2,1-4H3/t35-,36-,39-,40-,49+,50+,52-,53-/m0/s1
• InChI 密鑰: SWKRDCRSJPRVNF-DOGDSVMGSA-N

说明

應用

(DHQD)₂Pyr may be used:

• To catalyze the enantioselective allylic amination of alkylidene cyanoacetates with dialkyl azodicarboxylates.
• To prepare 10(R),11-Dihydroxydihydroquinine and 10(S),11-dihydroxydihydroquinine via the Sharpless catalytic asymmetric dihydroxylation.
• In the total synthesis of okadaic acid, a protein phosphatase inhibitor.

法律資訊

经 Rhodia Pharma Solutions 授权销售。

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves