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Merck

393835

Sigma-Aldrich

邻亚二甲苯基 N,N-二乙基亚磷酰胺

technical grade

别名:

3-(二乙氨基)-1,5-二氢-2,4,3-苯并二噁磷杂庚英

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About This Item

经验公式(希尔记法):
C12H18NO2P
CAS号:
分子量:
239.25
Beilstein:
3590087
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

品質等級

形狀

liquid

折射率

n20/D 1.541 (lit.)

bp

95-96 °C/0.1 mmHg (lit.)

溶解度

THF: soluble
acetonitrile: soluble
cold water: insoluble
dichloromethane: soluble

密度

1.109 g/mL at 25 °C (lit.)

官能基

amine

SMILES 字串

CCN(CC)P1OCc2ccccc2CO1

InChI

1S/C12H18NO2P/c1-3-13(4-2)16-14-9-11-7-5-6-8-12(11)10-15-16/h5-8H,3-4,9-10H2,1-2H3

InChI 密鑰

JDAKPBBWYIWXJF-UHFFFAOYSA-N

應用

o-Xylylene N,N-diethylphosphoramidite (N,N-diethyl-1,5-dihydro-2,4,3-benzodioxaphosphepin-3-amine) may be used in the synthesis of the following:
  • bicyclic glycosyl phosphite
  • pentakis(o-xylylene phosphate)
  • o-xylylene alkyl phosphites

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

188.6 °F - closed cup

閃點(°C)

87 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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分析证书(COA)

Lot/Batch Number

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Utilization of O-xylylene N,N-diethylphosphoramidite for the synthesis of phosphoric diesters.
Watanabe Y, et al
Tetrahedron Letters, 33(10), 1313-1316 (1992)
Honglu Zhang et al.
Organic letters, 11(7), 1551-1554 (2009-03-04)
The phosphorylated inositol diphosphates, including the diphosphoinositol pentakisphosphate regioisomers, play critical roles in signal transduction and cellular regulation. In particular, the IP(7) isomer 5-PP-Ins(1,2,3,4,6)P(5) is implicated in a nonenzymatic phosphate transfer converting a protein serine phosphate residue to a serine
Synergistic inhibition of human Synergistic inhibition of human α-1, 3-fucosyltransferase V.
Qiao L, et al
Journal of the American Chemical Society, 118(33), 7653-7662 (1996)

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