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Merck

364673

Sigma-Aldrich

乙基溴化镁 溶液

1.0 M in THF

别名:

EtMgBr溶液

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About This Item

线性分子式:
CH3CH2MgBr
CAS号:
分子量:
133.27
Beilstein:
3587203
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

品質等級

反應適用性

reaction type: Grignard Reaction

濃度

1.0 M in THF

密度

1.010 g/mL at 25 °C

SMILES 字串

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI 密鑰

TWTWFMUQSOFTRN-UHFFFAOYSA-M

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應用

乙基溴化镁溶液可用于格氏反应以及其他格氏试剂的合成。

其他說明

25℃以下储存可能会形成镁盐结晶。将容器移到温暖的位置,偶尔轻轻旋转,应该能使固体重新溶解。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Respiratory system

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 1

閃點(°F)

23.0 °F - closed cup

閃點(°C)

-5 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Replacement of the lactone moiety on podophyllotoxin and steganacin analogues with a 1, 5-disubstituted 1, 2, 3-triazole via ruthenium-catalyzed click chemistry.
Imperio D
Bioorganic & Medicinal Chemistry, 15(21), 6748-6757 (2007)
An improved synthesis of (+)-3, 4-O-isopropylidene butyne.
Jiang B
Synthetic Communications, 25(22), 3641-3645 (1995)
D R Hwang et al.
Nuclear medicine and biology, 27(6), 533-539 (2000-11-01)
Imaging neuroreceptors with radiolabeled agonists might provide valuable information on the in vivo agonist affinity states of receptors of interest. We report here the radiosynthesis, biodistribution in rodents, and imaging studies in baboons of [(11)C]-labeled (-)-N-propyl-norapomorphine [(-)-NPA]. (-)-[(11)C]NPA was prepared
M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction

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