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Merck

331023

Sigma-Aldrich

高氟叔丁醇

99%

别名:

1,1,1,3,3,3-六氟-2-三氟甲基-2-丙醇, 全氟叔丁醇

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About This Item

线性分子式:
(CF3)3COH
CAS号:
分子量:
236.04
Beilstein:
1841640
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.05

蒸汽壓力

5.19 psi ( 20 °C)

化驗

99%

形狀

liquid

折射率

n20/D 1.3 (lit.)

bp

45 °C (lit.)

密度

1.693 g/mL at 25 °C (lit.)

官能基

fluoro

SMILES 字串

OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F

InChI

1S/C4HF9O/c5-2(6,7)1(14,3(8,9)10)4(11,12)13/h14H

InChI 密鑰

XZNOAVNRSFURIR-UHFFFAOYSA-N

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一般說明

高氟丁醇也称为全氟丁醇和 ′人造血液′。

應用

高氟丁醇可用作制备适当的(聚氟烷氧基甲基)甲醇及其对应的甲磺酸盐的前体。

象形圖

Skull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Eyeshields, Faceshields, Gloves


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Huan Meng et al.
Organic letters, 21(13), 5206-5210 (2019-06-30)
A highly efficient method to incorporate the nonafluoro- tert-butoxy group into various arenes is developed. This C-O cross-coupling reaction proceeds smoothly in the absence of transition-metal catalyst with good functional group tolerance and scalability. In comparison with the conventional approach
Greener fluorous chemistry: Convenient preparation of new types of 'CF< sub> 3</sub>-rich'secondary alkyl mesylates and their use for the synthesis of azides, amines, imidazoles and imidazolium salts
Nemes A, et al.
Journal of Fluorine Chemistry, 131(12), 1368-1376 (2010)
Cyclization and rearrangement products from coupling reactions between terminal< i> o</i>-alkynylphenols or< i> o</i>-ethynyl (hydroxymethyl) benzene and 6-halopurines.
Berg TC, et al.
Tetrahedron, 62(25), 6121-6131 (2006)
Maxime Bourguignon et al.
Macromolecular rapid communications, 42(3), e2000482-e2000482 (2020-10-14)
Polyurethane hydrogels are attractive materials finding multiple applications in various sectors of prime importance; however, they are still prepared by the toxic isocyanate chemistry. Herein the facile and direct preparation in water at room temperature of a large palette of

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