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Merck
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文件

302015

Sigma-Aldrich

5-己炔-1-醇

96%

别名:

1-己炔-6-醇, 1-羟基-5-己炔, 5-己炔醇, 5-己醇, 6-羟基-1-己炔

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About This Item

线性分子式:
HC≡C(CH2)4OH
CAS号:
928-90-5
分子量:
98.14
Beilstein:
1739774
MDL號碼:
MFCD00002980
分類程式碼代碼:
12352100
PubChem物質ID:
24858225
NACRES:
NA.22

化驗

96%

形狀

liquid

折射率

n20/D 1.450 (lit.)

bp

73-75 °C/15 mmHg (lit.)

密度

0.89 g/mL at 25 °C (lit.)

SMILES 字串

OCCCCC#C

InChI

1S/C6H10O/c1-2-3-4-5-6-7/h1,7H,3-6H2

InChI 密鑰

GOQJMMHTSOQIEI-UHFFFAOYSA-N

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應用

5-己炔-1-醇被用于合成：
  • 肉桂醇稠环烯啶
  • llycopodium生物碱，(+)-nankakurine A以及(+)-nankakurine B
  • 7-苯甲酰氧基-3-(2-硝基苯硒基)-1,5-环十烷

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

158.0 °F - closed cup

閃點（°C）

70 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

分析证书(COA)

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M Michida et al.
Nucleic acids symposium series, (37)(37), 55-56 (1997-01-01)
7-Benzoyloxy-3-(2-nitrophenylseleno)-1,5-cyclodecadiyne (13) was prepared from 5-hexyn-1-ol and propargyl bromide via 10-iodo-7-(t-butyldiphenylsiloxy)-5,9-decadiynal (10). The facile cyclization of the acyclic precursor 10 would be rationalized in terms of "bulky group (TBDPSO) assisted conformational control". Oxidation of 13 by NaIO4, followed by thermal
Olga V Vinogradova et al.
The Journal of organic chemistry, 76(16), 6937-6941 (2011-07-02)
A short and efficient synthesis of cinnoline-fused cyclic enediyne is reported. Richter cyclization of o-(1,3-butadiynyl)phenyltriazene produced 3-alkynyl-4-bromocinnoline. The Sonogashira coupling of the latter with 5-hexyn-1-ol was employed for the introduction of a second acetylenic moiety. The crucial cyclization step was
Ryan A Altman et al.
The Journal of organic chemistry, 75(22), 7519-7534 (2010-10-21)
The first total syntheses of the Lycopodium alkaloids (+)-nankakurine A (2), (+)-nankakurine B (3), and the originally purported structure 1 of nankakurine A were accomplished. The syntheses of 2 and 3 feature a demanding intramolecular azomethine imine cycloaddition as the
Johanna E Grimm et al.
Journal of agricultural and food chemistry, 67(20), 5838-5846 (2019-05-06)
An aroma extract dilution analysis applied to the volatiles isolated from jackfruit ( Artocarpus heterophyllus Lam.) pulp by solvent extraction and solvent-assisted flavor evaporation resulted in the detection of 48 odorants with flavor dilution (FD) factors between 1 and ≥8192.
Wenqiang Tan et al.
Carbohydrate polymers, 160, 163-171 (2017-01-25)
Four novel 1,2,3-triazolium-functionalized starch derivatives were synthesized by N-alkylating the precursor starch derivatives with 1,2,3-triazole with iodomethane based on cuprous-catalyzed azide-alkyne cycloaddition (CuAAC). The detailed structural characterization was investigated by means of FTIR, UV-vis
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Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydroboration; oxidative cleavage; C–C coupling; and cycloadditions

Functionalized Alkynes

Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydroboration; oxidative cleavage; C–C coupling; and cycloadditions

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