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Merck

277460

Sigma-Aldrich

3-(甲硫基)丙醛

96%

别名:

3-(甲基巯基)丙醛, 3-(甲硫基)丙醛, NSC 15874, 甲硫基丙醛

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About This Item

线性分子式:
CH3SCH2CH2CHO
CAS号:
分子量:
104.17
Beilstein:
1739289
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

>1 (vs air)

品質等級

蒸汽壓力

760 mmHg ( 165 °C)

化驗

96%

形狀

liquid

折射率

n20/D 1.483 (lit.)

bp

165-166 °C (lit.)

密度

1.043 g/mL at 25 °C (lit.)

官能基

aldehyde
thioether

儲存溫度

2-8°C

SMILES 字串

CSCCC=O

InChI

1S/C4H8OS/c1-6-4-2-3-5/h3H,2,4H2,1H3

InChI 密鑰

CLUWOWRTHNNBBU-UHFFFAOYSA-N

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相关类别

一般說明

3-(甲硫基)丙醛 (methional) 是食品中通过 Strecker 降解进行化学蛋氨酸转化的主要产物

應用

3-甲硫基丙醛用作以下反应试剂:
  • 氧化偶联和化学选择性氧化
  • 分子间炔烃的氢化酰化反应
  • 硫化物氧化为亚砜
也用作乙烯生物合成的前体

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

165.2 °F - closed cup

閃點(°C)

74 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Ethylene formation from methional.
W A Pryor et al.
Biochemical and biophysical research communications, 81(2), 498-503 (1978-03-30)
M M W Etschmann et al.
Applied microbiology and biotechnology, 80(4), 579-587 (2008-07-04)
Yeasts can convert amino acids to flavor alcohols following the Ehrlich pathway, a reaction sequence comprising transamination, decarboxylation, and reduction. The alcohols can be further derivatized to the acetate esters by alcohol acetyl transferase. Using L: -methionine as sole nitrogen
F Amárita et al.
FEMS microbiology letters, 204(1), 189-195 (2001-10-30)
Lactic acid bacteria were screened for methional production from 4-methylthio-2-ketobutanoate. Only Lactococcus lactis IFPL730 produced high amounts of methional. It was demonstrated that production of this compound was an exclusively enzymatic reaction. The present work describes for the first time
A Vallet et al.
Journal of applied microbiology, 104(6), 1833-1840 (2008-01-26)
Determination of pathways involved in synthesis of volatile sulphur compounds (VSC) from methionine by Oenococcus oeni isolated from wine. Production of VSC by O. oeni from methionine was investigated during bacterial cultures and in assays performed in the presence of
Kerstin Burseg et al.
Journal of agricultural and food chemistry, 57(19), 9086-9090 (2009-09-19)
A novel technology (Olfactoscan screening) was applied to screen for volatiles including saturated aldehydes that mask the perception of methional, an off-flavor commonly found in orange juice. For the screening experiment, methional odor pulses were generated by an olfactometer and

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