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Sigma-Aldrich

三(三甲基硅基)磷

≥98%

别名:

磷酸三(三甲基硅基)酯

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About This Item

线性分子式:
[(CH3)3SiO]3P(O)
CAS号:
10497-05-9
分子量:
314.54
Beilstein:
1794624
EC號碼:
234-028-1
MDL號碼:
MFCD00008267
分類程式碼代碼:
12352100
PubChem物質ID:
24856672
NACRES:
NA.22

化驗

≥98%

形狀

liquid

折射率

n20/D 1.409 (lit.)

bp

228-229 °C/720 mmHg (lit.)

mp

3-4 °C (lit.)

密度

0.945 g/mL at 25 °C (lit.)

SMILES 字串

C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C

InChI

1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3

InChI 密鑰

QJMMCGKXBZVAEI-UHFFFAOYSA-N

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相关类别

一般說明

已经研究了三(三甲基甲硅烷基)磷酸酯作为LiNi0.5Co0.2Mn0.3O2 的新型成膜添加剂，用于在LiPF6电解质中以高截止电位循环。 三(三甲基甲硅烷基)磷酸酯[磷酸的三(三甲基甲硅烷基)酯]与环铝氮烷发生脱烷基甲硅烷基化反应，得到杂金刚烷分子。

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Danger

危險分類

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

55.4 °F - closed cup

閃點（°C）

13 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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The use of [18O4]phosphoric acid in the quantitation of phosphate by gas-liquid chromatography-mass spectrometry analysis.
G Graff et al.
Analytical biochemistry, 107(2), 324-331 (1980-09-15)
Tris (trimethylsilyl) phosphate: A film-forming additive for high voltage cathode material in lithium-ion batteries.
Yan G, et al.
Journal of Power Sources, 248, 1306-1311 (2014)
A Garcia-Casas et al.
Colloids and surfaces. B, Biointerfaces, 181, 973-980 (2019-08-07)
Sol-gel coatings are proposed as surface treatments for titanium-based materials to promote the osseointegration of prosthetic devices with the host. As precursors of sol-gel synthesis, two silanes were selected: 3-methacryloxypropyltrimethoxy silane and 2 tetramethyl orthosilane. Sol-gel synthesis was functionalized with
Jiri Pinkas et al.
Inorganic chemistry, 41(25), 6914-6918 (2002-12-10)
A dealkylsilylation reaction between alumazene [2,6-(i-Pr)(2)C(6)H(3)NAlMe](3) (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (MeAl)[2,6-(i-Pr)(2)C(6)H(3)N](3)[Al[OP(OSiMe(3))(3)]](2)(O(3)POSiMe(3)) (3). Compound 3 was characterized by analytical and spectroscopic methods, and its molecular structure was established

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