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271438

Sigma-Aldrich

三丁基乙烯基锡

97%

别名:

三丁基乙烯基锡, 三正丁基(乙烯基)锡, 乙烯基三丁基锡

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About This Item

线性分子式:
CH2=CHSn[CH3(CH2)3]3
CAS号:
7486-35-3
分子量:
317.10
Beilstein:
3537662
EC號碼:
231-291-4
MDL號碼:
MFCD00009421
分類程式碼代碼:
12352103
PubChem物質ID:
24856437
NACRES:
NA.22

化驗

97%

折射率

n20/D 1.478 (lit.)

bp

104-106 °C/3.5 mmHg (lit.)

密度

1.085 g/mL at 25 °C (lit.)

SMILES 字串

CCCC[Sn](CCCC)(CCCC)C=C

InChI

1S/3C4H9.C2H3.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;1H,2H2;

InChI 密鑰

QIWRFOJWQSSRJZ-UHFFFAOYSA-N

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一般說明

三丁基（乙烯基）锡是一种有机锡烷，常用于钯催化的交叉偶联反应。

應用

溴乙炔和溴代芳族化合物的乙烯基亲核试剂。

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

109.4 °F - closed cup

閃點（°C）

43 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBL3395
SHBH7759
06519CJ
10219BJ
10626KD

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The Journal of Organic Chemistry, 59, 7164-7164 (1994)
Masahiro Yoshida et al.
Organic letters, 6(12), 1979-1982 (2004-06-05)
[reaction: see text] A novel type of cascade ring expansion process has been developed by the palladium-catalyzed reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. The reaction proceeds in a stereospecific manner to produce (Z)-2-(3-aryl-1-propenyl)cyclopentanones. It has also been found that regioselective
Ernesto G Occhiato et al.
Journal of medicinal chemistry, 47(14), 3546-3560 (2004-06-25)
New 5alpha-reductase 1 (5alphaR-1) inhibitors were designed to complete a consistent set of analogues suitable for a 3D QSAR study. These compounds were synthesized by a modification of the aza-Robinson annulation, further functionalized by Pd-catalyzed cross-coupling processes, and were tested
R Skoda-Földes et al.
Steroids, 60(12), 812-816 (1995-12-01)
Direct and carbonylative coupling reactions of various steroid derivatives possessing iodo- and bromo-alkenyl moiety (17-iodo-androst-16-ene, 1, 17-bromoandrost-2,16-diene, 2, 17-iodo-4-aza-4-methylandrost-16-en-3-one, 3, 17-iodo-4-azaandrost-16-en-3-one, 4) with vinyltributylstannane and ethynyltributylstannane were carried out in the presence of various palladium catalysts. While carbonylation took place

商品

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

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