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Merck

255831

Sigma-Aldrich

氯化锗(IV)

99.999% trace metals basis

别名:

四氯化锗

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About This Item

线性分子式:
GeCl4
CAS号:
分子量:
214.45
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

等級

for analytical purposes

蒸汽壓力

76 mmHg ( 20 °C)

化驗

99.999% trace metals basis

形狀

liquid

反應適用性

reagent type: catalyst
core: germanium

雜質

≤15.0 ppm Trace Metal Analysis

bp

83 °C (lit.)

mp

−49.5 °C (lit.)

密度

1.88 g/mL at 25 °C

SMILES 字串

Cl[Ge](Cl)(Cl)Cl

InChI

1S/Cl4Ge/c1-5(2,3)4

InChI 密鑰

IEXRMSFAVATTJX-UHFFFAOYSA-N

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應用

用于通过微波法制备 Ge2Cl6,这是一种无色结晶物质,用于低价锗化合物的深入研究。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3

標靶器官

Respiratory system

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Does not sustain combustion.

閃點(°C)

Does not sustain combustion.

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ian R. Beattie et al.
Inorganic chemistry, 37(23), 6032-6034 (2001-10-24)
The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is very moisture-sensitive and decomposes readily in vacuo to give GeCl(4)
Zehui Zhang et al.
ChemSusChem, 4(1), 131-138 (2011-01-13)
Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides D-fructose and D-glucose, disaccharides sucrose and maltose, and even the polysaccharide cellulose were
Murat Kaya et al.
Talanta, 84(1), 122-126 (2011-02-15)
A new chloride generation system was designed for the direct, sensitive, rapid and accurate determination of the total germanium in complex matrices. It was aimed to improve the detection limit of chloride generation technique by increasing the vapor pressure of
Amit Pratap Singh et al.
Journal of the American Chemical Society, 134(10), 4998-5003 (2012-02-15)
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl(+)) and anionic (MCl(3)(-)) species
Sung Ki Cho et al.
Journal of the American Chemical Society, 137(20), 6638-6642 (2015-05-06)
We demonstrate the feasibility of semiconductor deposition via the electrochemical reduction of gaseous precursors by the use of an anhydrous proton-conducting membrane, the solid acid CsHSO4, at 165 °C. This membrane electrode assembly was operated within the oxidation of hydrogen

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