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Merck

218367

Sigma-Aldrich

( S) - (−) -柠檬烯

96%

别名:

(-)-对薄荷-1,8-二烯, (-)-香芹烯, (S)-4-异丙烯基-1-甲基环己烯

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About This Item

经验公式(希尔记法):
C10H16
CAS号:
分子量:
136.23
Beilstein:
2323991
EC號碼:
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

4.7 (vs air)

品質等級

蒸汽壓力

<3 mmHg ( 14.4 °C)
1 mmHg ( 20 °C)

化驗

96%

形狀

liquid

光學活性

[α]19/D −94°, c = 10 in ethanol

expl. lim.

6.1 %

折射率

n20/D 1.471 (lit.)

bp

175-177 °C (lit.)

密度

0.844 g/mL at 25 °C (lit.)

SMILES 字串

CC(=C)[C@H]1CCC(C)=CC1

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m1/s1

InChI 密鑰

XMGQYMWWDOXHJM-SNVBAGLBSA-N

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一般說明

( S )-(-)-柠檬烯,为单萜类化合物 ,多用于香料和调味剂。在辐照条件下,它会发生辐解,导致光学纯度降低。( S )-(-)-柠檬烯也显示出有效的抗菌活性。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

123.8 °F - closed cup

閃點(°C)

51 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Antimicrobial activity of limonene enantiomers and 1, 8-cineole alone and in combination.
Van Vuuren SF and Viljoen AM.
Flavour and Fragrance Journal, 22(6), 540-544 (2007)
Malaria parasites produce volatile mosquito attractants.
Kelly M, et al.
mBio, 6(2), e00235-e00215 (2015)
Gamma-radiolysis of chiral molecules: R (+)-limonene, S (-)-limonene and R (-)-a-phellandrene.
Cataldo F, et al.
J. Radioanal. Nucl. Chem., 262(2), 423-428 (2004)
P L Crowell et al.
Critical reviews in oncogenesis, 5(1), 1-22 (1994-01-01)
The naturally occurring monoterpene d-limonene has chemopreventive and chemotherapeutic activity against many rodent solid tumor types. The chemopreventive activity of limonene during initiation can be attributed to the induction of phase I and phase II enzymes, with resulting carcinogen detoxification.
P A Cornwell et al.
The Journal of pharmacy and pharmacology, 46(12), 938-950 (1994-12-01)
Wide-angle X-ray-diffraction experiments were used to investigate the molecular organization of barrier components of human stratum corneum. Diffraction lines related to the side-by-side lipid packing arrangements in the intercellular bilayers were identified as were patterns arising from secondary protein structures

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