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208353

Sigma-Aldrich

五氯化钼

95%

别名:

Molybdenum pentachloride, Pentachloromolybdenum

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About This Item

线性分子式:
MoCl5
CAS号:
10241-05-1
分子量:
273.21
MDL號碼:
MFCD00003467
分類程式碼代碼:
12352302
PubChem物質ID:
24852509
NACRES:
NA.23

蒸汽壓力

1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)

品質等級

100

化驗

95%

形狀

powder

反應適用性

reagent type: catalyst
core: molybdenum

雜質

<0.5% insoluble matter

bp

268 °C (lit.)

mp

194 °C (lit.)

密度

2.928 g/mL at 25 °C (lit.)

應用

battery manufacturing

SMILES 字串

Cl[Mo](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5

InChI 密鑰

GICWIDZXWJGTCI-UHFFFAOYSA-I

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相关类别

一般說明

氯化钼（V）是一种路易斯酸，被广泛用作许多有机反应的催化剂和试剂。它可以由钼金属的直接氯化或亚硫酰氯和 MoO3的加热回流制备。

應用

氯化钼（V）可用作以下反应的高效催化剂：
  • 硝基苯和醇的缩合以及烯基锂试剂的C-C偶联。
  • 苄基醇与磺胺和氨基甲酸酯的直接酰胺化反应。
它可用于烷基卤化物、烯烃和炔烃的氯化反应。

它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体，用于化学选择性羰基烯化反应。

象形圖

Health hazardCorrosion
GHS08,GHS05

訊號詞

Danger

危險聲明

H314,H351

危險分類

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number
MKCQ3154
MKCP8343
MKCP1674
MKCJ9980
MKCJ0802

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二甲基胺锂 95%

Sigma-Aldrich

296066

二甲基胺锂

Kumar, S. Manickam, M.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
Mladen Litvić et al.
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
H I Ogawa et al.
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Kristina Hackeloer et al.
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Simon Trosien et al.
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular

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Solid-State Metathesis Materials Synthesis

In the last two decades, a new method termed solid-state metathesis (SSM) has been developed to synthesize compounds that are often difficult to produce conventionally.

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