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蒸汽壓力
1.5 mmHg ( 20 °C)
品質等級
化驗
97%
形狀
solid
mp
157-160 °C (lit.)
溶解度
H2O: very slightly soluble
H2O: very soluble
alcohol: miscible
diethyl ether: miscible
organic solvents: very soluble
SMILES 字串
C1CN2CCC1CC2
InChI
1S/C7H13N/c1-4-8-5-2-7(1)3-6-8/h7H,1-6H2
InChI 密鑰
SBYHFKPVCBCYGV-UHFFFAOYSA-N
基因資訊
rat ... Chrm1(25229)
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一般說明
Quinuclidine is a bicyclic tertiary amine with a bridgehead nitrogen atom structure, often used in the synthesis of iodonium complexes and as a hydrogen-atom-transfer (HAT) catalyst in photo induced reactions.
應用
奎宁环可用作以下反应的催化剂：
- 醛与丙烯酸甲酯的贝里斯-希尔曼反应。
- α-甲基葡萄糖转化为α-甲基阿洛糖的差向异构化反应。
訊號詞
Danger
危險分類
Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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H P Kertscher et al.
Die Pharmazie, 46(11), 772-774 (1991-11-01)
A series of 13 PAF-analogues with heterocyclane head groups and variation of the P-N-distance on the C-3-position of the backbone were synthesized. The proaggregatory and inhibitory potencies on rabbit and human blood platelets in vitro was evaluated. Investigations of structure-activity
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Efficient microwave-assisted three-component one-pot preparation of 1-aryl-4-(2-acetoxyethyl) piperazines and 1-aryl-4-(2-acetoxyethyl) piperidines
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Yong Wang et al.
Nature, 578(7795), 403-408 (2020-01-16)
Glycans have diverse physiological functions, ranging from energy storage and structural integrity to cell signalling and the regulation of intracellular processes1. Although biomass-derived carbohydrates (such as D-glucose, D-xylose and D-galactose) are extracted on commercial scales, and serve as renewable chemical
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