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Merck

178713

Sigma-Aldrich

9-硼双环[3.3.1]壬烷二聚体

别名:

9-BBN

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About This Item

经验公式(希尔记法):
C16H30B2
CAS号:
分子量:
244.03
Beilstein:
605509
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

形狀

solid

品質等級

反應適用性

reagent type: reductant

mp

150-152 °C (lit.)

SMILES 字串

C1C[C@H]2CCC[C@@H](C1)B2B3[C@H]4CCC[C@@H]3CCC4

InChI

1S/C16H28B2/c1-5-13-7-2-8-14(6-1)17(13)18-15-9-3-10-16(18)12-4-11-15/h13-16H,1-12H2/t13-,14+,15-,16+

InChI 密鑰

IYDIZBOKVLHCQZ-GEEKYZPCSA-N

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應用

已发现将过氧酯还原为醇(不伴随过氧键还原)的试剂。
用于炔烃、腈类、和酮类的硼氢化反应。
空气稳定的结晶试剂,用于将环状缩醛和缩酮还原裂解为单苄化 1,2-二醇。

象形圖

FlameExclamation mark

訊號詞

Danger

危險分類

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

Lot/Batch Number

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其他客户在看

Slide 1 of 1

1 of 1

Hong-Xia Jin et al.
The Journal of organic chemistry, 70(11), 4240-4247 (2005-05-21)
Reduction of organic molecules that contain a peroxy bond is broadly considered as a "risky" and uncertain operation when cleavage of the peroxy linkage is not desired. For this reason, such reduction steps are normally avoided at the planning stage
Tetrahedron Letters, 32, 6239-6239 (1991)
Chemische Berichte, 126, 285-285 (1993)
Synlett, 349-349 (1991)
Organic Process Research & Development, 10, 1076-1076 (2006)

商品

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

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