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Merck
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16350

Sigma-Aldrich

溴苯

≥99.5% (GC)

别名:

1-Bromobenzene, Bromobenzol, Monobromobenzene, Phenyl bromide

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About This Item

经验公式（希尔记法）:
C6H5Br
CAS号:
108-86-1
分子量:
157.01
Beilstein:
1236661
EC號碼:
203-623-8
MDL號碼:
MFCD00000055
分類程式碼代碼:
12352100
PubChem物質ID:
57647528
NACRES:
NA.22

蒸汽密度

5.41 (vs air)

品質等級

200

蒸汽壓力

10 mmHg ( 40 °C)

化驗

≥99.5% (GC)

形狀

liquid

自燃溫度

1051 °F

expl. lim.

36.5 %

折射率

n20/D 1.559 (lit.)
n20/D 1.559

bp

156 °C (lit.)

mp

−31 °C (lit.)

溶解度

alcohol: soluble 10.4g/100g at 25 °C
diethyl ether: soluble 71.3g/100g at 25 °C
water: insoluble 0.045g/100g at 30 °C (practically)
benzene: miscible
chloroform: miscible
hydrocarbons: miscible (petr.)

密度

1.491 g/mL at 25 °C (lit.)

官能基

bromo

SMILES 字串

Brc1ccccc1

InChI

1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H

InChI 密鑰

QARVLSVVCXYDNA-UHFFFAOYSA-N

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相关类别

應用

溴苯被用于合成制备两亲性星形接枝共聚物所需的四臂星形链转移剂 。

生化／生理作用

溴苯通过形成反应性代谢产物芳香化重要的细胞大分子，诱导肝坏死 。

訊號詞

Warning

危險聲明

H226,H315,H411

危險分類

Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

123.8 °F - closed cup

閃點（°C）

51.0 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
BCCF7091
BCCC3505
BCCB2050
BCBW5525
BCBT5468

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Star-like PAA-g-PPO well-defined amphiphilic graft copolymer synthesized by ATNRC and SET-NRC reaction.
Li Y, et al.
Journal of Polymer Science: Part A, General Papers, 48(10), 2084-2097 (2010)
Bromobenzene-induced liver necrosis. Protective role of glutathione and evidence for 3,4-bromobenzene oxide as the hepatotoxic metabolite.
D J Jollow et al.
Pharmacology, 11(3), 151-169 (1974-01-01)
Xiaolin Pan et al.
Organic & biomolecular chemistry, 10(10), 1969-1975 (2012-01-26)
Diverse 11H-indeno[1,2-c]quinolines are produced via a palladium-catalyzed three-component reaction of 2-alkynylbromobenzene, 2-alkynylaniline, and electrophile. This conversion tolerates a wide variety of functionality and substitution patterns on the 11H-indeno[1,2-c]quinoline ring.
Hiroyuki Asakura et al.
The journal of physical chemistry. A, 116(16), 4029-4034 (2012-04-14)
A homocoupling reaction mechanism of bromobenzene mediated by the [Ni(cod)(bpy)] (cod = 1,5-cyclooctadiene; bpy = 2,2'-bipyridine) complex was investigated by means of in situ time-resolved X-ray absorption fine structure (XAFS) and factor analysis. A dimer intermediate [Ni(bpy)(Ph)Br](2) proposed in the
Lukas Werner et al.
The Journal of organic chemistry, 76(24), 10050-10067 (2011-10-20)
Four generations of chemoenzymatic approaches to oseltamivir are presented. The first two generations relied on the use of cyclohexadiene-cis-diol derived enzymatically from bromobenzene. The third and fourth generation used the corresponding diol obtained from ethyl benzoate by fermentation with E.
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实验方案

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

US EPA Method 8260 describes the analysis of volatile organic compounds in solid wastes and ground waters. This application illustrates the analysis of many compounds commonly analyzed by this method using purge and trap coupled to GC-MS.

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