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Merck

159042

Sigma-Aldrich

Luperox®P,-过氧苯甲酸丁酯

98%

别名:

过氧化苯甲酸叔丁酯, 过氧化叔丁基苯甲酸酯

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About This Item

线性分子式:
C6H5COOOC(CH3)3
CAS号:
分子量:
194.23
Beilstein:
1342734
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

6.7 (vs air)

品質等級

蒸汽壓力

3.36 mmHg ( 50 °C)

化驗

98%

形狀

liquid

折射率

n20/D 1.499 (lit.)

bp

75-76 °C/0.2 mmHg (lit.)

溶解度

water: soluble 1.18 g/L

密度

1.021 g/mL at 25 °C (lit.)

官能基

peroxide
phenyl

SMILES 字串

CC(C)(C)OOC(=O)c1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3

InChI 密鑰

GJBRNHKUVLOCEB-UHFFFAOYSA-N

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一般說明

报道了过氧化苯甲酸特丁酯(TBPB)-介导的2-异氰基二芳基插入1,4-二氧六环。

應用

氧化苯甲酸叔丁酯用作聚合和交联催化剂。它还在以下期间用作引发剂:
  • 2,2,6,6-四甲基-1-哌啶氧基(TEMPO)-4-氧乙酰胺基-(3-丙基三乙氧基硅烷)接枝到聚(乙烯共聚辛烯)上
  • 通过起始化学气相沉积制备共形聚(甲基丙烯酸环己酯)薄膜

法律資訊

Arkema Inc. 产品
Luperox is a registered trademark of Arkema Inc.

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

200.1 °F - closed cup

閃點(°C)

93.4 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD synthesis. Using TBPOB instead of
Structural comparison of products from peroxide-initiated grafting of vinylsilane and silane-functionalized nitroxyl to hydrocarbon and polyolefin substrates.
Weaver JD, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 46(13), 4542-4555 (2008)
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Chemical communications (Cambridge, England), 50(49), 6439-6442 (2014-04-05)
An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H bond functionalization under metal-free conditions.
Chengguo Liu et al.
Polymers, 11(5) (2019-05-10)
New tung oil (TO)-based, unsaturated, co-ester (Co-UE) macromonomers bearing steric hindrance were synthesized by modifying a TO-based maleate (TOPERMA) monomer with an anhydride structure with hydroxyethyl methacrylate (HEMA) and methallyl alcohol (MAA), respectively. The obtained Co-UE monomers (TOPERMA-HEMA and TOPERMA-MAA)
Margaret Hanausek et al.
Carcinogenesis, 25(3), 431-437 (2003-11-25)
Screening of newly synthesized organic peroxides for tumor initiating/promoting activity would be greatly facilitated if predictive methodologies could be developed using topical exposures shorter than those required for definitive tumor assessment in mouse skin models. Nine organic peroxides [benzoyl peroxide

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