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蒸汽壓力
1 mmHg ( 100 °C)
化驗
96%
形狀
liquid
折射率
n20/D 1.534 (lit.)
bp
144 °C/10 mmHg (lit.)
275-278 °C (lit.)
密度
1.291 g/mL at 25 °C (lit.)
SMILES 字串
Cc1ccc(cc1)S(=O)(=O)N=C=O
InChI
1S/C8H7NO3S/c1-7-2-4-8(5-3-7)13(11,12)9-6-10/h2-5H,1H3
InChI 密鑰
VLJQDHDVZJXNQL-UHFFFAOYSA-N
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一般說明
对甲苯磺酰基异氰酸酯与烯丙基锡烷和烯丙基氯发生钯催化的双烯丙基化反应。
應用
对甲苯磺酰基异氰酸酯用作：
- LC-MS/MS法测定人血浆中3-α-羟基替勃龙的衍生化试剂
- HPLC法同时定量分析药物中二甘醇和丙二醇的衍生化试剂
- 制备乙酰化顺-1,2-二醇、恶唑烷-2-酮、2,3-二氨基酸和N-甲苯磺酰基碳酰胺的试剂
訊號詞
Danger
危險分類
Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
294.8 °F - closed cup
閃點（°C）
146 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
N Solin et al.
Organic letters, 3(6), 909-912 (2001-03-27)
A tandem bis-allylation of p-toluenesulfonyl isocyanate can be achieved by palladium-catalyzed three-component coupling reaction with allylstannanes and allyl chlorides. A high level of regioselectivity can be obtained by the appropriate choice of the allylic substituents. The reaction mechanism and the
Fabiana Fernandes de Santana e Silva Cardoso et al.
Biomedical chromatography : BMC, 27(11), 1457-1462 (2013-07-03)
A new method was developed for the quantitation of 3-α-hydroxy tibolone, in human plasma, after oral administration of a tablet formulation containing tibolone (2.5 mg). 3-α-Hydroxy tibolone was extracted by a liquid-liquid procedure, using cyproterone acetate as internal standard and chlorobutane
Tetrahedron Letters, 34, 951-951 (1993)
Tetrahedron, 47, 2263-2263 (1991)
Tetrahedron Letters, 34, 1867-1867 (1993)
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