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化驗
97%
形狀
liquid
折射率
n20/D 1.386 (lit.)
bp
85-86 °C (lit.)
密度
0.868 g/mL at 25 °C (lit.)
SMILES 字串
CC(C)(C)N=C=O
InChI
1S/C5H9NO/c1-5(2,3)6-4-7/h1-3H3
InChI 密鑰
MGOLNIXAPIAKFM-UHFFFAOYSA-N
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一般說明
叔丁基异氰酸酯与磷杂环丙烯发生 [2 + 2] 环加成反应生成 1-氧杂-2-基环丁烷 。它还与二氧钼 双 （芳氧基）配合物发生环加成反应，生成新型的 16 电子钼氧亚胺 双 （芳氧基）配合物 。微量水存在下与二氢铝反应生成末端氢氧化铝 。
應用
叔丁基异氰酸酯可用于：
- 制备异氰酸酯处理的石墨氧化物 ( i GOs)，可在极性非质子溶剂中进行剥离，得到氧化石墨烯纳米片。
- 对金属有机骨架进行后综合修饰，得到微孔尿素功能化骨架。
- 以二氢铝为原料合成末端氢氧化铝。
訊號詞
Danger
危險分類
Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
24.8 °F - closed cup
閃點（°C）
-4 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
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Inorganic chemistry, 43(4), 1217-1219 (2004-02-18)
A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCH=N-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) was prepared by treatment of aluminum dihydride LAlH2 (1) and tert-butyl isocyanate in the presence of trace amounts of water and alternatively from 1 and
L W Wattenberg
Cancer research, 41(8), 2991-2994 (1981-08-01)
The effects of sodium cyanate, tert-butyl isocyanate, and benzyl isothiocyanate on carcinogen-induced neoplasia were studied in experiments in which the test compound was fed starting 1 week following completion of carcinogen administrations. Under these conditions, all three test compounds exerted
Dumitru Ghereg et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(45), 12763-12772 (2011-10-01)
Phosphagermaallene Tip(tBu)Ge=C=PMes* 1 (Tip=2,4,6-triisopropylphenyl, Mes*=2,4,6-tri-tert-butylphenyl) reacts with phenyl isocyanate and tert-butyl isocyanate by a [2+2] cycloaddition that involves the Ge=C and C=O double bonds to afford 1-oxa-2-germacyclobutanes 2 and 3. With N,N'-dicyclohexylcarbodiimide, a [2+2] cycloaddition is observed between the Ge=C
Warren B Cross et al.
Inorganic chemistry, 45(11), 4556-4561 (2006-05-23)
The novel 16-electron molybdenum oxo-imido bis(aryloxide) complexes [Mo(NtBu)(O)(2,6-Me2C6H3O)2(py)] (1) and [Mo(NtBu)(O)(2,6-iPr2C6H3O)2(py)] (2) have been prepared by the salt elimination reactions of [Mo(NtBu)(O)Cl2(DME)] with the appropriate lithium aryloxide and from the cycloaddition reactions of tert-butyl isocyanate with the appropriate molybdenum dioxo
Emily Dugan et al.
Chemical communications (Cambridge, England), (29)(29), 3366-3368 (2008-07-18)
Isoreticular metal-organic framework-3 (IRMOF-3) has been postsynthetically modified with isocyanates to generate unprecedented, microporous urea-functionalized frameworks.
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