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化驗
98%
形狀
liquid
折射率
n20/D 1.4540 (lit.)
bp
130-132 °C (lit.)
密度
0.828 g/mL at 25 °C (lit.)
SMILES 字串
C#CC1CCCCC1
InChI
1S/C8H12/c1-2-8-6-4-3-5-7-8/h1,8H,3-7H2
InChI 密鑰
SSDZYLQUYMOSAK-UHFFFAOYSA-N
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一般說明
环己基乙炔(乙炔基环己烷)与肝微粒体孵育时介导 NADPH 依赖性细胞色素 P-450 损失 。
應用
环己基乙炔(乙炔基环己烷)用于制备 [Os [(E)-CH = CHR] (= C = C = CPh2) (CH3CN) 2 (P (i) Pr3) 2] BF4 (R = Ph,Cy) 。
訊號詞
Danger
危險聲明
危險分類
Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
64.4 °F - closed cup
閃點(°C)
18 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Self-catalyzed inactivation of hepatic cytochrome P-450 by ethynyl substrates.
The Journal of biological chemistry, 255(12), 5578-5585 (1980-06-25)
Journal of the American Chemical Society, 128(12), 3965-3973 (2006-03-23)
Treatment in acetonitrile at -30 C of the hydride-alkenylcarbyne complex [OsH([triple bond]CCH=CPh2)(CH3CN)2(P(i)Pr3)2][BF4]2 (1) with (t)BuOK produces the selective deprotonation of the alkenyl substituent of the carbyne and the formation of the bis-solvento hydride-allenylidene derivative [OsH(=C=C=CPh2)(CH3CN)2(P(i)Pr3)2]BF4 (2), which under carbon monoxide
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