146552

Benzyltriethylammonium chloride

99%

• Synonyme(s) : BTEAC
• Formule linéaire : C₆H₅CH₂N(Cl)(C₂H₅)₃
• Numéro CAS: 56-37-1
• Poids moléculaire : 227.77
• Numéro Beilstein : 3574984
• Numéro CE : 200-270-1
• Numéro MDL: MFCD00011824
• Code UNSPSC : 12352107
• ID de substance PubChem : 24848786
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 200
• Pureté: 99%
• Forme: solid
• Pf: 190-192 °C (dec.) (lit.)
• Chaîne SMILES: [Cl-].CC[N+](CC)(CC)Cc1ccccc1
• InChI: 1S/C13H22N.ClH/c1-4-14(5-2,6-3)12-13-10-8-7-9-11-13;/h7-11H,4-6,12H2,1-3H3;1H/q+1;/p-1
• Clé InChI: HTZCNXWZYVXIMZ-UHFFFAOYSA-M

Description

Application

Benzyltriethylammonium chloride is a lipophilic phase-transfer catalyst that can be used in phase-transfer catalysis (PTC) to catalyze polycondensation reactions to form high molecular weight polymers under bi-phasic conditions.

It can also be used:

• To activate hydroxyapatite and natural phosphate for use as a solid support for Knoevenagel condensation and Claisen-Schmidt condensation, respectively at room temperature and in the absence of a solvent.
• To increase the efficiency of mCPBA oxidation of sulfonimine generated from arenesulfonamide and diethyl acetal of an aromatic aldehyde to form 2-sulfonyloxaziridines.
• In combination with antimony(V) chloride to form a catalytic system for the Friedel-Crafts acylation reactions of arenes with acyl and sulfonyl chlorides.

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H315,H319,H335
• Conseils de prudence: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): >527.0 °F - closed cup
• Point d'éclair (°C): > 275 °C - closed cup
• Équipement de protection individuelle: dust mask type N95 (US), Eyeshields, Gloves