383074

Bismuth(III) nitrate pentahydrate

ACS reagent, ≥98.0%

• Fórmula lineal: Bi(NO₃)₃ · 5H₂O
• Número de CAS: 10035-06-0
• Peso molecular: 485.07
• Número CE: 233-791-8
• Código UNSPSC: 12352302
• ID de la sustancia en PubChem: 24863932
• NACRES: NB.24

Propiedades

• grado: ACS reagent
• Nivel de calidad: 200
• Ensayo: ≥98.0%
• Formulario: (Powder or Crystals or Solid or Chunks)
• idoneidad de la reacción: reagent type: catalyst; core: bismuth
• impurezas: ≤0.005% insolubles
• bp: 75-80 °C (lit.)
• mp: 30 °C (lit.)
• trazas de anión: chloride (Cl^-): ≤0.001%; sulfate (SO₄^2-): ≤0.005%
• trazas de catión: Ag: ≤0.001%; As: ≤0.001%; Ca: ≤0.005%; Cu: ≤0.002%; Fe: ≤0.001%; K: ≤0.01%; Na: ≤0.02%; Pb: ≤0.002%
• cadena SMILES: O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
• InChI: 1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
• Clave InChI: DPLOIMSBRDLLRI-UHFFFAOYSA-N

Descripción

Descripción general

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.

Aplicación

Bismuth(III) nitrate pentahydrate may be used in the following processes:

• Conversion of thioamides and thioureas to their oxo derivatives.
• Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.
• Synthesize coumarins by Pechmann condensation under solvent free conditions.
• As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.
• As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.
• As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.
• Synthesis of glycosides by Fischer glycosylation of unprotected sugars.
• Synthesis of bismuth oxide (Bi₂O₃) nanoparticles.
• Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.
• Selective oxidation of sufides to sulfoxides.

Información de seguridad

• Pictogramas: GHS03,GHS05
• Palabra de señalización: Danger
• Frases de peligro: H272,H318
• Consejos de prudencia: P210 - P220 - P280 - P305 + P351 + P338 - P370 + P378 - P501
• Clasificaciones de peligro: Eye Dam. 1 - Ox. Sol. 2
• Código de clase de almacenamiento: 5.1B - Oxidizing hazardous materials
• Clase de riesgo para el agua (WGK): WGK 2
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable