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775118

Sigma-Aldrich

Borane dimethyl sulfide complex solution

greener alternative

1.0 M in 2-methyltetrahydrofuran

Sinónimos:

BMS, Trihydro[thiobis[methane]]boron

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About This Item

Fórmula lineal:
(CH3)2S · BH3
Número de CAS:
13292-87-0
Peso molecular:
75.97
Beilstein:
3663489
Número MDL:
MFCD00013189
Código UNSPSC:
12352112
ID de la sustancia en PubChem:
329767736
NACRES:
NA.22

Formulario

liquid

idoneidad de la reacción

reagent type: reductant

características de los productos alternativos más sostenibles

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentración

1.0 M in 2-methyltetrahydrofuran

densidad

0.844 g/mL at 25 °C

grupo funcional

thioether

categoría alternativa más sostenible

, Aligned

temp. de almacenamiento

2-8°C

cadena SMILES

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

Clave InChI

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

Aplicación

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.
For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane
Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

Envase

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Información legal

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1

Riesgos supl.

EUH019

Código de clase de almacenamiento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

9.3 °F

Punto de inflamabilidad (°C)

-12.6 °C

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Certificados de análisis (COA)

Lot/Batch Number
SHBL6342
SHBK2868
SHBJ1749
SHBG1668V
SHBC9981

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