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Merck

431567

Sigma-Aldrich

Lithium perchlorate

greener alternative

99.99% trace metals basis

Sinónimos:

Perchloric acid, lithium salt

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About This Item

Fórmula lineal:
LiClO4
Número de CAS:
Peso molecular:
106.39
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.23

grado

ACS reagent

Nivel de calidad

Análisis

99.99% trace metals basis

formulario

granular

idoneidad de la reacción

reagent type: oxidant

características de los productos alternativos más sostenibles

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sustainability

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impurezas

≤0.005% insolubles
<100 ppm total metallic impurities

pH

6.0-7.5

mp

236 °C (lit.)

solubilidad

H2O: 106.4 g/L at 20 °C

trazas de anión

chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤0.001%

categoría alternativa más sostenible

cadena SMILES

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

Clave InChI

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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Descripción general

Lithium perchlorate is a white salt that easily dissolves in water. It is commonly employed as an electrolytic salt in batteries due to its excellent electrical impedance, conductivity, hygroscopicity, and anodic stability properties. These characteristics are crucial for its role in battery applications. In addition, it is as a strong oxidizing agent and hence is used as an oxidizer in solid rocket propellants and organic reactions.
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Aplicación

Lithium perchlorate can be used:
  • As a precursor to prepare solid polymer electrolytes for rechargeable Li-ion batteries.
  • As an oxidizer to prepare polymer-based solid propellants.
  • To fabricate cobalt sulfide (CoS)-based counter electrode for dye-sensitized solar cells(DSSC).
Our Lithium perchlorate, with a 99.99% trace metals basis, possesses specific specifications that make it ideal for Lithium-ion batteries. It has low levels of anion traces such as chloride (Cl-): ≤0.003%and sulfate (SO42-): ≤0.001%. Additionally, it contains less than 5 ppm of heavy metals, further enhancing its suitability as an electrolytic salt for Lithium-ion batteries.

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

5.1A - Strongly oxidizing hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
L H Sim et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 287-292 (2010-05-07)
The interaction behaviours between components of polyacrylate (PAc)/poly(ethylene oxide) (PEO) and lithium perchlorate (LiClO(4)) were investigated in detail by Attenuated Total Reflectance (ATR)-Fourier Transformed Infrared (FTIR) spectroscopy. Solution cast films of the PAc/PEO and PAc/PEO/LiClO(4) were examined. No obvious shifting
Natalia Varaksa et al.
Proceedings of the National Academy of Sciences of the United States of America, 99(8), 5012-5017 (2002-04-18)
The adsorption of the trigonal connector, 1,3,5-tris[10-(3-ethylthiopropyl)dimethylsilyl-1,10-dicarba-closo-decaboran-1-yl]benzene (1), from acetonitrile/0.1 M LiClO(4) on the surface of mercury at potentials ranging from +0.3 to -1.4 V (vs. aqueous Ag/AgCl/1 M LiCl) was examined by voltammetry, Langmuir isotherms at controlled potentials, and
Witold Darlewski et al.
Journal of hazardous materials, 175(1-3), 460-467 (2009-11-17)
A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
Francisco Palacios et al.
The Journal of organic chemistry, 67(7), 2131-2135 (2002-04-02)
Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium

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