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Merck

216224

Sigma-Aldrich

Kaliumpersulfat

ACS reagent, ≥99.0%

Synonym(e):

KPS, Kaliumperoxodisulfat

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About This Item

Lineare Formel:
K2S2O8
CAS-Nummer:
Molekulargewicht:
270.32
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.21

Qualität

ACS reagent

Qualitätsniveau

Dampfdichte

9.3 (vs air)

Dampfdruck

<0.1 hPa ( 25 °C)

Assay

≥99.0%

Form

powder or crystals

Eignung der Reaktion

reagent type: catalyst
reaction type: C-H Activation

reagent type: oxidant

Verunreinigungen

≤0.001% Cl compounds
≤0.005% insolubles

pH-Wert

2.5-4.5 (25 °C, 27 g/L)

Kationenspuren

Fe: ≤5 ppm
Mn: ≤2 ppm
heavy metals (as Pb): ≤0.001%

SMILES String

[K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2K.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChIKey

USHAGKDGDHPEEY-UHFFFAOYSA-L

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Allgemeine Beschreibung

Potassium persulfate is a water-soluble inorganic salt that releases oxygen and exhibits a strongly exothermic reaction. It is stable at room temperature but decomposes at high temperatures. Potassium persulfate is commonly used as an oxidant and in the polymerization of numerous monomers, mainly in the field of hydrogel synthesis.

Anwendung


  • Aggregation-induced electrochemiluminescence enhancement of Ag-MOG for amyloid β 42 sensing.: This study demonstrates the use of potassium persulfate in the aggregation-induced electrochemiluminescence enhancement of Ag-MOG for sensitive detection of amyloid β 42, relevant in Alzheimer′s disease research (Zheng et al., 2023).

  • Optimization of preparation conditions and performance of a new degradable soil water retaining agent.: This research investigates the role of potassium persulfate in optimizing the preparation and performance of a novel degradable soil water-retaining agent, highlighting its potential in agricultural applications (Yumang et al., 2024).

  • A superabsorbent and pH-responsive copolymer-hydrogel based on acemannan from Aloe vera (Aloe barbadensis M.): A smart material for drug delivery.: This article explores the synthesis of a pH-responsive hydrogel incorporating potassium persulfate, demonstrating its application in drug delivery systems (Irfan et al., 2024).

  • Silver-Catalyzed Carbofluorination of Olefins and α-Fluoroolefins with Carbamoyl Radicals.: The study describes a novel silver-catalyzed carbofluorination reaction facilitated by potassium persulfate, offering advancements in synthetic organic chemistry (Vincent & Brioche, 2024).

  • Sustained release delivery of favipiravir through statistically optimized, chemically cross-linked, pH-sensitive, swellable hydrogel.: This research utilizes potassium persulfate in the development of a pH-sensitive hydrogel for the controlled release of favipiravir, enhancing therapeutic efficacy (Khan et al., 2024).

Potassium persulfate is used as an oxidizing agent:

  • in the oxidation of 4-Chloro-3-methylphenol in pressurized hot water and supercritical water in a continuous flow system.
  • in determinations of dissolved organic carbon.
Potassium persulfate (KPS) has also been used as a redox initiator :

  • in the graft polymerization of acrylonitrile onto starch in aqueous solution.
  • in the synthesis of sulfate radical anions via polymerization processes.
  • as polymerization and radical initiator in the synthesis of polyacrylamide-Laponite-lead dioxide nanoparticle hydrogel composites by acrylamide as monomers.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Toughening polystyrene by core-shell grafting copolymer polybutadiene-graft-polystyrene with potassium persulfate as initiator.
Di Cai G, et al.
Journal of Industrial and Engineering Chemistry (Amsterdam, Netherlands), 19(3), 823-828 (2013)
Potassium persulfate promoted catalytic wet oxidation of fulvic acid as a model organic compound in landfill leachate with activated carbon.
Xu XY, et al.
Chemical Engineering Journal, 200, 25-31 (2012)
Free radical degradation of chitosan with potassium persulfate.
Hsu SC, et al.
Polymer Degradation and Stability, 75(1), 73-83 (2002)
Bernaurdshaw Neppolian et al.
Water research, 44(12), 3687-3695 (2010-04-27)
The sonochemical oxidation of As(III) in the presence of peroxydisulfate ion (PDS) has been investigated. Sulfate anion radicals and OH radicals produced during acoustic cavitation readily oxidized As(III) to As(V) in an aqueous environment. The rate of oxidation of As(III)
Huan Niu et al.
Biosensors & bioelectronics, 26(7), 3175-3180 (2011-01-18)
A novel label free electrochemiluminescence (ECL) immunosensor based on the ECL of peroxydisulfate solution for detection of α-1-fetoprotein (AFP) has been developed. For this proposed immunosensor, L-cysteine was firstly electrodeposited on the gold electrode surface, which promoted the electron transfer

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