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Wichtige Dokumente
M1875
Natriummalonat, dibasisch Monohydrat
≥98% (non-aqueous titration)
Synonym(e):
Malonsäure Dinatriumsalz, Propandisäure Dinatriumsalz Monohydrat
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About This Item
Lineare Formel:
CH2(CO2Na)2 · H2O
CAS-Nummer:
Molekulargewicht:
166.04
Beilstein:
3772420
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Assay
≥98% (non-aqueous titration)
SMILES String
O.[Na].OC(=O)CC(O)=O
InChI
1S/C3H4O4.2Na/c4-2(5)1-3(6)7;;/h1H2,(H,4,5)(H,6,7);;/q;2*+1/p-2
InChIKey
PRWXGRGLHYDWPS-UHFFFAOYSA-L
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Allgemeine Beschreibung
Sodium malonate dibasic monohydrate, also known as Malonic acid disodium salt monohydrate, is commonly used as a building block in organic reaction for synthesizing complex compounds.
Anwendung
Sodium malonate dibasic monohydrate can be used as a ligand to synthesize:
- Bis(cyclopentadienyl)molybdenum malonate using molybdenocene dichloride in the presence of water.
- Malonato complexes of manganese using manganese dichloride and 1,10-phenanthroline in the presence of methanol.
- Metal-organic based polymeric complex using transition metal compound and urotropine.
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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Idainés Feliciano et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 14(7), 1109-1117 (2009-06-19)
Two water-soluble molybdenocene complexes containing oxygen chelating ligands, maltolato and malonate, have been synthesized to elucidate the role of the ancillary ligands in the molybdenocene cytotoxic activity. The structural characterizations of these species by 1H NMR and IR spectroscopies suggest
Sanjit Konar et al.
Inorganic chemistry, 42(8), 2545-2552 (2003-04-15)
Two new metal-organic based polymeric complexes, [Cu(4)(O(2)CCH(2)CO(2))(4)(L)].7H(2)O (1) and [Co(2)(O(2)CCH(2)CO(2))(2)(L)].2H(2)O (2) [L = hexamethylenetetramine (urotropine)], have been synthesized and characterized by X-ray crystal structure determination and magnetic studies. Complex 1 is a 1D coordination polymer comprising a carboxylato bridged Cu(4)
Milya Davlieva et al.
Nucleic acids research, 43(9), 4758-4773 (2015-04-22)
LiaR is a 'master regulator' of the cell envelope stress response in enterococci and many other Gram-positive organisms. Mutations to liaR can lead to antibiotic resistance to a variety of antibiotics including the cyclic lipopeptide daptomycin. LiaR is phosphorylated in
Alessio Innocenti et al.
Bioorganic & medicinal chemistry, 17(7), 2654-2657 (2009-03-20)
The inhibition of the beta-carbonic anhydrases (CAs, EC 4.2.1.1) from the pathogenic fungi Cryptococcus neoformans (Can2) and Candida albicans (Nce103) with carboxylates such as the C1-C5 aliphatic carboxylates, oxalate, malonate, maleate, malate, pyruvate, lactate, citrate and some benzoates has been
Alessio Innocenti et al.
Bioorganic & medicinal chemistry letters, 15(3), 573-578 (2005-01-25)
A detailed inhibition study of five carbonic anhydrase (CA, EC 4.2.1.1) isozymes with carboxylates including aliphatic (formate, acetate), dicarboxylic (oxalate, malonate), hydroxy/keto acids (l-lactate, l-malate, pyruvate), tricarboxylic (citrate), or aromatic (benzoate, tetrafluorobenzoate) representatives, some of which are important intermediates in
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