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Sigma-Aldrich

Borandimethylsulfid-Komplex -Lösung

greener alternative

1.0 M in 2-methyltetrahydrofuran

Synonym(e):

BMS, Trihydro[thiobis[methane]]boron

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About This Item

Lineare Formel:
(CH3)2S · BH3
CAS-Nummer:
13292-87-0
Molekulargewicht:
75.97
Beilstein:
3663489
MDL-Nummer:
MFCD00013189
UNSPSC-Code:
12352112
PubChem Substanz-ID:
329767736
NACRES:
NA.22

Form

liquid

Eignung der Reaktion

reagent type: reductant

Grünere Alternativprodukt-Eigenschaften

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Konzentration

1.0 M in 2-methyltetrahydrofuran

Dichte

0.844 g/mL at 25 °C

Funktionelle Gruppe

thioether

Grünere Alternativprodukt-Kategorie

, Aligned

Lagertemp.

2-8°C

SMILES String

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChIKey

RMHDLBZYPISZOI-UHFFFAOYSA-N

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Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

Anwendung

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.
For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane
Reactant used as a regioselective reducing agent

Reactant involved in:
  • Hydroboration / oxidation
Synthesis of cage compounds

Verpackung

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Rechtliche Hinweise

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1

Zusätzliche Gefahrenhinweise

EUH019

Lagerklassenschlüssel

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flammpunkt (°F)

9.3 °F

Flammpunkt (°C)

-12.6 °C

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
SHBL6342
SHBK2868
SHBJ1749
SHBG1668V
SHBC9981

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