763284

9-Azabicyclo[3.3.1]nonan N-Oxyl

95%

• Synonym(e): 9-Azabicyclo[3.3.1]nonane N-oxyl Radikal, ABNO
• Empirische Formel (Hill-System): C₈H₁₄NO
• CAS-Nummer: 31785-68-9
• Molekulargewicht: 140.20
• Beilstein: 1681761
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329767041
• NACRES: NA.22

Eigenschaften

• Assay: 95%
• Form: solid
• Eignung der Reaktion: reagent type: ligand
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp (Schmelzpunkt): 65-70 °C
• Grünere Alternativprodukt-Kategorie: , Aligned
• Lagertemp.: 2-8°C
• SMILES String: C[C@@]12CCC[C@@](C)(CCC1)N2[O]
• InChI: 1S/C10H18NO/c1-9-5-3-7-10(2,11(9)12)8-4-6-9/h3-8H2,1-2H3/t9-,10+
• InChIKey: GGWCZKZSILYISB-AOOOYVTPSA-N

Beschreibung

Allgemeine Beschreibung

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) belongs to a sterically unhindered and stable class of nitroxyl radicals. It efficiently catalyzes the oxidation of alcohols to afford the corresponding carbonyl compounds. ABNO along with (^MeObpy)Cu^I(OTf) (^MeObpy =4,4′-dimethoxy-2,2′-bipyridine) comprises a catalytic system. This catalytic system is useful for the aerobic oxidation of all categories of alcohols.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) may be employed for the aerobic oxidation of alcohols.

Catalytic oxidant for copper-catalyzed greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H302,H318
• P-Sätze: P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable