668540

(2S,5S)-(-)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-Imidazolidinon

95%

• Synonym(e): (2S,5S)-3-Methyl-2-(5-methyl-2-furanyl)-5-(phenylmethyl)-4-imidazolidinon
• Empirische Formel (Hill-System): C₁₆H₁₈N₂O₂
• CAS-Nummer: 415678-40-9
• Molekulargewicht: 270.33
• MDL-Nummer: MFCD08457653
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24884991
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 95%
• Brechungsindex: n20/D 1.5598
• Funktionelle Gruppe: phenyl
• SMILES String: CN1[C@H](N[C@@H](Cc2ccccc2)C1=O)c3ccc(C)o3
• InChI: 1S/C16H18N2O2/c1-11-8-9-14(20-11)15-17-13(16(19)18(15)2)10-12-6-4-3-5-7-12/h3-9,13,15,17H,10H2,1-2H3/t13-,15-/m0/s1
• InChIKey: IQIMPHPFMHVWBZ-ZFWWWQNUSA-N

Beschreibung

Anwendung

Catalyst for:

• Enantioselective organocatalytic transfer hydrogenation of cycloalkenones with tert-Bu Hantzsch ester as source of hydrogen
• Alkylation of indoles with an α,β-disubstituted α,β-unsaturated aldehyde in the enantioselective preparation of a selective serotonin reuptake inhibitor
• MacMillan reaction

Highly selective organocatalyst for the Diels-Alder reaction with simple α,β−unsaturated ketones.

Rechtliche Hinweise

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Sicherheitshinweise

• Piktogramme: GHS06
• Signalwort: Danger
• H-Sätze: H301,H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P301 + P310 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flammpunkt (°F): >230.0 °F
• Flammpunkt (°C): > 110 °C
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges