429007

1-Propinylmagnesiumbromid -Lösung

0.5 M in THF

• Synonym(e): 1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium
• Lineare Formel: CH₃C≡CMgBr
• CAS-Nummer: 16466-97-0
• Molekulargewicht: 143.26
• Beilstein: 3929146
• MDL-Nummer: MFCD00216588
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24866829
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 0.5 M in THF
• bp: 65-67 °C
• Dichte: 0.941 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: CC#C[Mg]Br
• InChI: 1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
• InChIKey: YVJBCTFVENNIOV-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

1-Propynylmagnesiumbromide solution is 1-propynylmagnesium bromide in 0.5M tetrahydrofuran.1-propynylmagnesium bromide solution used as a Grignard reagent in chemical synthesis. This research reagent can be used for chemical and organic transformations. It is used as a regent in the conversion of [11C]CO2 to [11C] amides via Mitsunobu reaction.

Anwendung

Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H261,H302,H314,H335,H336,H351
• P-Sätze: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 30.2 °F - closed cup
• Flammpunkt (°C): -1 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter