224448

Phenylmagnesiumchlorid -Lösung

2.0 M in THF

• Synonym(e): Chlorophenylmagnesium
• Lineare Formel: C₆H₅MgCl
• CAS-Nummer: 100-59-4
• Molekulargewicht: 136.86
• Beilstein: 3587900
• MDL-Nummer: MFCD00000464
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24853438
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 2.0 M in THF
• Dichte: ~1.02 g/mL at 20 °C; 1.042 g/mL at 25 °C
• SMILES String: Cl[Mg]c1ccccc1
• InChI: 1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
• InChIKey: GQONLASZRVFGHI-UHFFFAOYSA-M

Beschreibung

Anwendung

Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (−)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl₃) in the rechargeable magnesium batteries.

Verpackung

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Sonstige Hinweise

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07,GHS08
• Signalwort: Danger
• H-Sätze: H225 - H314 - H335 - H336 - H351
• P-Sätze: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter