- A modular synthesis of dithiocarbamate pendant unnatural α-amino acids.
A modular synthesis of dithiocarbamate pendant unnatural α-amino acids.
Chemical communications (Cambridge, England) (2012-07-21)
Amit Saha, R B Nasir Baig, John Leazer, Rajender S Varma
PMID22814637
ABSTRACT
Unnatural α-amino acids containing dithiocarbamate side chains were synthesized by a one-pot reaction of in situ generated dithiocarbamate anions with sulfamidates. A wide range of these anions participated in the highly regio- and stereo-selective ring opening of sulfamidates to produce the corresponding dithiocarbamate pendant α-amino acids in high yields.
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