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32213

Sigma-Aldrich

Metanolo

≥99.8% (GC), ACS reagent, suitable for immunofluorescence, reag. Ph. Eur., reag. ISO, USP/NF

Sinonimo/i:

Alcol metilico

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About This Item

Formula condensata:
CH3OH
Numero CAS:
Peso molecolare:
32.04
Beilstein:
1098229
Numero CE:
Numero MDL:
Codice UNSPSC:
12352104
ID PubChem:
NACRES:
NA.05

Nome del prodotto

Metanolo, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)

Grado

ACS reagent
puriss. p.a.

Livello qualitativo

agenzia

USP/NF
reag. ISO
reag. Ph. Eur.

Densità del vapore

1.11 (vs air)

Tensione di vapore

410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

Saggio

≥99.8% (GC)

Stato

liquid

Temp. autoaccensione

725 °F

Limite di esplosione

36 %

tecniche

immunofluorescence: suitable

Impurezze

≤0.00005% free alkali (as NH3)
≤0.0001% formaldehyde
≤0.00025% KMnO4 red. matter (as O)
≤0.0005% non-volatile matter
≤0.001% acetaldehyde
≤0.001% acetone (GC)
≤0.05% water (Karl Fischer)
≤0.1% ethanol (GC)

Indice di rifrazione

n20/D 1.329 (lit.)

P. ebollizione

64.7 °C (lit.)

Punto di fusione

−98 °C (lit.)

Densità

0.791 g/mL at 25 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤0.5 mg/kg
sulfate (SO42-): ≤1 mg/kg

Cationi in tracce

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.01 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.01 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.02 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Stringa SMILE

CO

Formato

neat

InChI

1S/CH4O/c1-2/h2H,1H3
OKKJLVBELUTLKV-UHFFFAOYSA-N

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Descrizione generale

Methanol is an organic solvent that can be synthesized from syngas in the presence of CuO/ZnO/Al2O3 catalysts. It is an ideal candidate as a hydrogen source in fuel cell technology due to its high H/C ratio, low propensity for soot generation, relatively low reforming temperature and as it exists in liquid state at room temperature. In a direct methanol fuel cell (DMFC), methanol undergoes oxidation with air to generate electricity. The olefins (ethylene or propylene) formed from methanol via MTO (methanol-to-olefins) process, can be an alternate to oil and gas to produce hydrocarbon fuels.
Thermochemical conversion of methanol to C2-C10 hydrocarbons in the presence of shape-selective zeolites has been reported. Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.

Applicazioni

Methanol was used in the following studies:
  • Colony forming unit-fibroblast assay of bone marrow mononuclear cells.
  • As solvent for the preparation of extracts of hyphae of Aspergillus for the estimation of gliotoxin by reversed phase-HPLC.
  • Immunofluorescence studies.

Confezionamento

In PE-bottles; also available Glass-bottles (Material no. ending with *-GL)

Altre note

The article number 32213-4X2.5L will be discontinued. Please order the single bottle 32213-2.5L which is physically identical with the same exact specifications.
The article number 32213-4X2.5L-M will be discontinued. Please order the single bottle 32213-2.5L-M which is physically identical with the same exact specifications.
The article number 32213-4X5L will be discontinued. Please order the single bottle 32213-5L which is physically identical with the same exact specifications.
The article number 32213-6X1L will be discontinued. Please order the single bottle 32213-1L which is physically identical with the same exact specifications.

Prodotti correlati

N° Catalogo
Descrizione
Determinazione del prezzo

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Organi bersaglio

Eyes,Central nervous system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

49.5 °F - closed cup

Punto d’infiammabilità (°C)

9.7 °C - closed cup


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Beyond oil and gas: the methanol economy.
Olah GA.
Angewandte Chemie (International Edition in English), 44(18), 2636-2639 (2005)
Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies.
Jadhav SG, et al.
Chemical Engineering Research and Design, 92(11), 2557-2567 (2014)
Methanol steam reforming for hydrogen generation via conventional and membrane reactors: a review.
Iulianelli A, et al.
Renewable and Sustainable Energy Reviews, 29, 355-368 (2014)
Review of methanol reforming-Cu-based catalysts, surface reaction mechanisms, and reaction schemes.
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International Journal of Hydrogen Energy, 38(22), 9541-9552 (2013)
Robert E Schwartz et al.
The Journal of clinical investigation, 109(10), 1291-1302 (2002-05-22)
We have derived from normal human, mouse, and rat postnatal bone marrow primitive, multipotent adult progenitor cells (MAPCs) that can differentiate into most mesodermal cells and neuroectodermal cells in vitro and into all embryonic lineages in vivo. Here, we show

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