237051
Aluminum chloride
ReagentPlus®, 99%
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About This Item
Formula condensata:
AlCl3
Numero CAS:
Peso molecolare:
133.34
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
eCl@ss:
38120507
ID PubChem:
NACRES:
NA.21
Saggio:
99%
Stato:
powder
Prodotti consigliati
Tensione di vapore
1 mmHg ( 100 °C)
Livello qualitativo
Nome Commerciale
ReagentPlus®
Saggio
99%
Stato
powder
Impiego in reazioni chimiche
reagent type: catalyst
core: aluminum
pH
2.4 (20 °C, 100 g/L)
Punto di fusione
190 °C (lit.)
Stringa SMILE
Cl[Al](Cl)Cl
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
VSCWAEJMTAWNJL-UHFFFAOYSA-K
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Categorie correlate
Descrizione generale
Aluminum chloride is an alcohol-soluble lewis acid.† Aluminum chloride mixed with sodium borohydride, in diglyme in a molar ratio affords a mixture having strong reducing properties.† It was reported to promote the Friedel-Crafts acylation reaction between 4-tert-butylbenzoyl chloride and mesitylene.†
Applicazioni
Aluminum chloride was used for the following studies:
- Polymerization of benzene to afford p-polyphenyl.
- As a catalyst for the Friedel-Crafts acylation of buckymetallocenes with the acid chlorides.
- As a catalyst for the colorimetric microassay for the determination of lipid hydroperoxides.
Caratteristiche e vantaggi
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.
Note legali
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Avvertenze
Danger
Indicazioni di pericolo
Classi di pericolo
Eye Dam. 1 - Skin Corr. 1B
Rischi supp
Codice della classe di stoccaggio
8A - Combustible corrosive hazardous materials
Classe di pericolosità dell'acqua (WGK)
WGK 1
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
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I clienti hanno visto anche
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p-Polyphenyl from Benzene-Lewis Acid Catalyst-Oxidant. Reaction Scope and Investigation of the Benzene-Aluminum Chloride-Cupric Chloride System1.
Kovacic P and Oziomek J.
The Journal of Organic Chemistry, 29(1), 100-104 (1964)
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Dalton transactions (Cambridge, England : 2003), 43(20), 7407-7412 (2013-10-26)
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Rajkumar Kore et al.
Dalton transactions (Cambridge, England : 2003), 47(23), 7795-7803 (2018-06-01)
Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 - x)AlCl3 + xZnCl4] double salt ionic
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