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82270

Sigma-Aldrich

1,2-Dichloropropane

99%

Sinonimo/i:

Propylene dichloride

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About This Item

Formula condensata:
CH3CHClCH2Cl
Numero CAS:
78-87-5
Peso molecolare:
112.99
Beilstein:
1718880
Numero CE:
201-152-2
Numero MDL:
MFCD00000868
Codice UNSPSC:
12352100
ID PubChem:
329769241
NACRES:
NA.22

Densità del vapore

3.89 (vs air)

Tensione di vapore

40 mmHg ( 19.4 °C)

Saggio

99%

Stato

liquid

Temp. autoaccensione

1035 °F

Limite di esplosione

14.5 %

Indice di rifrazione

n20/D 1.439 (lit.)
n20/D 1.439

P. ebollizione

95-96 °C (lit.)

Punto di fusione

−100 °C (lit.)

Densità

1.156 g/mL at 25 °C (lit.)

Gruppo funzionale

chloro

Stringa SMILE

CC(Cl)CCl

InChI

1S/C3H6Cl2/c1-3(5)2-4/h3H,2H2,1H3
KNKRKFALVUDBJE-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

1,2-Dichloropropane, also known as Propylene dichloride, is a chlorinated solvent, that is commonly utilized as an intermediate in the synthesis of basic organic chemicals.

Applicazioni

1,2-Dichloropropane can be used as a building block to synthesize:
  •  2-Ylidene-1,3-dithiolane derivatives via one-pot reaction with carbon disulfide and active methylene compounds in the presence of sodium ethylate.      
  • β-Chloropropylsulfurs by controllable dechloro-coupling reaction with thiols.      
  • Thiazolidine and 1,3-thiazinane derivatives via [3+2] and [3+3] annulation reaction with β-ketothioamides in the presence of phosphonium ylide as a catalyst.

Avvertenze

Danger

Indicazioni di pericolo

H225,H302,H331,H350

Classi di pericolo

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

59.0 °F - closed cup

Punto d’infiammabilità (°C)

15.0 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCBZ4348
BCCG3939
BCCD8106
BCCC6511
BCBV6320

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Sigma-Aldrich

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Sigma-Aldrich

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Monish Arbaz Ansari et al.
Organic & biomolecular chemistry, 17(41), 9151-9162 (2019-10-09)
Phosphonium ylides are being reported here as a catalyst for the formation of thiazolidines and 1,3-thiazinanes from β-ketothioamides (which act as a three atom N, C, and S synthon) with dihaloalkanes via [3 + 2] and [3 + 3] annulations
Synthesis of some 2-ylidene-1, 3-dithiolanes
Lipin KV, et al.
Russ. J. Org. Chem., 53(1), 147-149 (2017)
H D Kirk et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 28(1), 18-26 (1995-11-01)
1,2-Dichloropropane (PDC) was evaluated for its potential to cause embryonal/fetal toxicity and teratogenicity in pregnant rats and rabbits. PDC was administered via oral gavage at dose levels of 0, 10, 30, or 125 mg/kg/day on Days 6 through 15 of
A Odinecs et al.
Renal failure, 17(5), 517-524 (1995-09-01)
The contribution of testosterone to the nephrotoxic effects of 1,2-dichloropropane (DCP) was assessed by a series of castration and sex hormone replacement experiments on Wistar rats. The nephrotoxic action of DCP was evaluated by measuring the accumulation of organic anion
[Determination of 1, 2 propylene dichloride in air in working places].
Wei Chen et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 24(7), 440-441 (2006-08-08)
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