802948

(dppf)Ni(o-tolyl)Cl

• Sinonimo/i: Buchwald Ni Catalyst
• Formula empirica (notazione di Hill): C₄₁H₃₅ClFeNiP₂
• Numero CAS: 1501945-23-8
• Peso molecolare: 739.66
• Numero MDL: MFCD28411349
• Codice UNSPSC: 12161600
• ID PubChem: 329768766
• NACRES: NA.22

Proprietà

• Saggio: 95%
• Livello qualitativo: 100
• Stato: powder
• Impiego in reazioni chimiche: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• Punto di fusione: 173 °C
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe]
• InChI: 1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1; LGLPATFHWYLMCO-UHFFFAOYSA-M

Descrizione

Descrizione generale

(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph₃P)₂Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.

Informazioni sulla sicurezza

• Pittogrammi: GHS08,GHS09
• Avvertenze: Danger
• Indicazioni di pericolo: H317,H334,H341,H350,H360,H372,H410
• Consigli di prudenza: P201 - P273 - P280 - P302 + P352 - P308 + P313
• Classi di pericolo: Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation
• Codice della classe di stoccaggio: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable