798835

[Ru(phd)₃](PF₆)₂

• Sinonimo/i: Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• Formula empirica (notazione di Hill): C₃₆H₁₈F₁₂N₆O₆P₂Ru
• Numero CAS: 184023-77-6
• Peso molecolare: 1021.56
• Codice UNSPSC: 12352202
• ID PubChem: 329768673
• NACRES: NA.22

Proprietà

• Forma fisica: powder
• Impiego in reazioni chimiche: core: ruthenium; reagent type: catalyst
• Stringa SMILE: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2; LGAOGZFZNIEFHF-UHFFFAOYSA-N

Descrizione

Applicazioni

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Note legali

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 13 - Non Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable