692255

RuCl₂[(R)−DM−BINAP][(R)−DAIPEN]

• Sinonimo/i: Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(2R)−1,1−bis(4−methoxyphenyl)−3−methyl−1,2−butanediamine]ruthenium(ΙΙ)
• Formula empirica (notazione di Hill): C₇₁H₇₄Cl₂N₂O₂P₂Ru
• Numero CAS: 220114-32-9
• Peso molecolare: 1221.28
• Numero MDL: MFCD09753026
• Codice UNSPSC: 12352101
• ID PubChem: 329761478
• NACRES: NA.22

Proprietà

• Stato: powder
• Punto di fusione: 197-211 °C
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: COc1ccc(cc1)C2([NH2][Ru]3(Cl)(Cl)([NH2][C@@H]2C(C)C)[PH](c4cc(C)cc(C)c4)(c5cc(C)cc(C)c5)c6ccc7ccccc7c6-c8c(ccc9ccccc89)[PH]3(c%10cc(C)cc(C)c%10)c%11cc(C)cc(C)c%11)c%12ccc(OC)cc%12
• InChI: 1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/t;18-;;;/m.1.../s1; VMSNEARTLSFOHB-OEGAAENXSA-N

Descrizione

Applicazioni

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for:

• Noyori-type enantioselective ketone hydrogenation
• Enantioselective and asymmetric hydrogenation of ketones

Note legali

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable