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481521

Sigma-Aldrich

Hexaamminecobalt(III) chloride

99%

Sinonimo/i:

Cobalt hexammine trichloride, Hexaamminecobalt trichloride

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About This Item

Formula condensata:
[Co(NH3)6]Cl3
Numero CAS:
10534-89-1
Peso molecolare:
267.48
Numero CE:
234-103-9
Numero MDL:
MFCD00036304
Codice UNSPSC:
12352302
ID PubChem:
24871764
NACRES:
NA.23

Saggio

99%

Forma fisica

powder

Punto di fusione

217 °C (lit.)

Solubilità

H2O: slightly soluble(lit.)
ethanol: insoluble(lit.)

Densità

1.71 g/mL at 25 °C (lit.)

Stringa SMILE

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Co+3]

InChI

1S/3ClH.Co.6H3N/h3*1H;;6*1H3/q;;;+3;;;;;;/p-3
JXBGZYGSWFSYFI-UHFFFAOYSA-K

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Descrizione generale

Hexaamminecobalt(III) chloride can be used as a starting material to prepare various Co-based nanomaterials such as Co-Sb nanoalloys, Co nanocapsules, bimetallic nanoparticles, and Co-polymer nanocomposites. These materials are applied in the field of catalysis, dielectrics, and renewable energy conversion devices.

Applicazioni

  • Rhenium (VII) compounds as inorganic precursors for the synthesis of organic reaction catalysts: Investigates the potential of Hexaamminecobalt(III) chloride as a replacement for commercial products in catalyzing organic reactions, highlighting its role in synthetic chemistry (K Leszczyńska-Sejda et al., 2019).
  • In situ formation of a molecular cobalt (iii)/AgCl photocatalyst for visible-light water oxidation: Discusses the synthesis and application of Hexaamminecobalt(III) chloride in forming a novel photocatalyst for water oxidation, a critical process in solar energy utilization (H Mogi et al., 2021).

Pittogrammi

Health hazard
GHS08

Avvertenze

Danger

Indicazioni di pericolo

H317,H334,H351,H413

Classi di pericolo

Aquatic Chronic 4 - Carc. 2 - Resp. Sens. 1 - Skin Sens. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

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P M Littlewood et al.
Brain research, 445(1), 165-170 (1988-03-29)
Intracellular injection of hexamminecobaltic chloride into a neurone causes characteristic changes to the structure of its mitochondria. This provides a simple technique to label neuronal profiles for examination of their ultrastructure. Synaptic structures are not affected by hexamminecobaltic ions.
Pinpinat Malaikaew et al.
Journal of photochemistry and photobiology. B, Biology, 103(3), 251-255 (2011-05-03)
In this study, a new small-molecule-based reagent was designed to recognize and bind to specific site in protein. A new pyrenyl probe, d-biotinyl-1(1-pyrene)methylamide (Py-biotin) was designed and synthesized by coupling of d-biotin to 1(1-pyrene)methylamine hydrochloride. Binding studies and site-specific photocleavage
Michael G Poirier et al.
Journal of cellular biochemistry, 85(2), 422-434 (2002-04-12)
We show that the chromatin in mitotic chromosomes can be drastically overcompacted or unfolded by temporary shifts in ion concentrations. By locally 'microspraying' reactants from micron-size pipettes, while simultaneously monitoring the size of and tension in single chromosomes, we are
T Allers et al.
Nucleic acids research, 28(2), e6-e6 (1999-12-22)
The Holliday junction is a central intermediate in genetic recombination. This four-stranded DNA structure is capable of spontaneous branch migration, and is lost during standard DNA extraction protocols. In order to isolate and characterize recombination intermediates that contain Holliday junctions
D C Tessier et al.
Analytical biochemistry, 158(1), 171-178 (1986-10-01)
Despite its unique ability to ligate single-stranded DNA molecules, T4 RNA ligase has so far seen little use in molecular biology due to long reaction times, modest yields, and apparent inability to promote ligation of long oligodeoxyribonucleotides. We describe here
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