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430218

Sigma-Aldrich

Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone]

pellets, MDI-polyester/polyether polyurethane.

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About This Item

Numero CAS:
Numero MDL:
Codice UNSPSC:
12162002
NACRES:
NA.23

Resistenza all’abrasione

10 mg (Taber, H-22 wheel)

Stato

beads
pellets

Indice di fluidità

4 g/10 min (190°C/8.7kg)

Durezza

84 (Shore A, ASTM D 2240)

Temp. transizione

Tg −40 °C (DSC)
softening point 85 °C (Vicat, ASTM D 1525)

Densità

1.18 g/mL at 25 °C (lit.)

Stringa SMILE

N(c1ccc(cc1)Cc2ccc(cc2)NC(=O)O)C(=O)O.OCCCCCC(=O)O.OCCCCO.OCCCO

InChI

UTAMRXGORNGYAA-UHFFFAOYSA-N

Descrizione generale

Poly[4,4′-methylenebis(phenyl isocyanate)-alt-1,4-butanediol/di(propylene glycol)/polycaprolactone] (PU/PCL) is a polyurethane solution that can be used as a shape memory polymer and a reinforcing unit for enhancing the mechanical and thermal properties of the base materials. It is biocompatible and finds usage in endothelial proliferations. PU/PCL contains polycaprolactone (PCL) that facilitates the hydrophobic properties of the polymeric matrix.

Applicazioni

Automotive fascia, cable jackets, side trim, fabric laminates, health care tubing, catheters, transdermal patches and in seals casters, shoes, bushings and wheels.
PU/PCL can be used in the formation of a polyurethane membrane for effective gas separation. It can also be used to synthesize reinforced hydrogel with good thermo-mechanical properties for biomedical applications.

Caratteristiche e vantaggi

Tough, high-performance, wear-resistant elastomer with good clarity, chemical resistance, flexibility and toughness. Can be used in current form or further polymerized. Low compression set

Pittogrammi

Health hazardExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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Strong fiber reinforced hydrogels for biomedical applications
2011 IEEE 37th Annual Northeast Bioengineering Conference (NEBEC), 9(2), 1-2 (2011)
Gas separation in mixed matrix membranes based on polyurethane containing SiO2, ZSM-5, and ZIF-8 nanoparticles
Amedi HR and Aghajani M
Journal of Natural Gas Science and Engineering, 35(19), 695-702 (2016)
A hybrid electrospun PU/PCL scaffold satisfied the requirements of blood vessel prosthesis in terms of mechanical properties, pore size, and biocompatibility
Nguyen T, et al.
Journal of Biomaterials Science. Polymer Edition, 24(14), 1692-1706 (2013)
Mélusine Bouchet et al.
Materials science & engineering. C, Materials for biological applications, 100, 715-723 (2019-04-06)
The search for novel, more compliant vascular grafts for the replacement of blood vessels is ongoing, and predictive tools are needed to identify the most promising biomaterials. A simple analytical model was designed that enables the calculation of the ratio

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