28612

Trihexyltetradecylphosphonium bis(2,4,4-trimethylpentyl)phosphinate

≥90.0%

• Sinonimo/i: Tetradecyltrihexylphosphonium bis(2,4,4-trimethylpentyl)phosphinate
• Formula empirica (notazione di Hill): C₄₈H₁₀₂O₂P₂
• Numero CAS: 465527-59-7
• Peso molecolare: 773.27
• Numero MDL: MFCD04117696
• Codice UNSPSC: 12352100
• ID PubChem: 57648314
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: ≥90.0%
• Impurezze: ≤1.0% water
• Densità: 0.895 g/mL at 20 °C (lit.)
• Gruppo funzionale: phosphine
• Stringa SMILE: CC(CC(C)(C)C)CP([O-])(=O)CC(C)CC(C)(C)C.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC
• InChI: 1S/C32H68P.C16H35O2P/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;1-13(9-15(3,4)5)11-19(17,18)12-14(2)10-16(6,7)8/h5-32H2,1-4H3;13-14H,9-12H2,1-8H3,(H,17,18)/q+1;/p-1; ZKQLVOZSJHOZBL-UHFFFAOYSA-M

Descrizione

Descrizione generale

Trihexyltetradecylphosphonium bis(2,4,4-trimethylpentyl)phosphinate is a phosphonium-based ionic liquid. It can be prepared by reacting trihexyl(tetradecyl)-phosphonium chloride with bis(2,4,4-trimethylpentyl)phosphinic acid in the presence of a base.

http://www.sigmaaldrich.com/dam/sigma-aldrich/docs/Aldrich/Acta/al_acta_37_1.pdf

Applicazioni

It can be used as an extractant for the removal of dibenzothiophene from liquid fuels via extractive desulfurization (EDS).

Caratteristiche e vantaggi

Phosphonium-based ionic liquid possess interesting properties such as:

• Liquid at room temperature or melting at T <100 °C
• High thermal stability
• Immiscible with water
• Soluble in organic solvents (however, when an excess of water is added to the system, three liquid phases are formed)
• Stable under basic conditions

Altre note

A phosphonium phosphinate for use as a polar solvent

Informazioni sulla sicurezza

• Pittogrammi: GHS05
• Avvertenze: Danger
• Indicazioni di pericolo: H314
• Consigli di prudenza: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• Classi di pericolo: Skin Corr. 1B
• Codice della classe di stoccaggio: 8A - Combustible corrosive hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter