255025

Hexylmagnesium bromide solution

2.0 M in diethyl ether

• Sinonimo/i: 1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
• Formula condensata: CH₃(CH₂)₅MgBr
• Numero CAS: 3761-92-0
• Peso molecolare: 189.38
• Beilstein: 3535624
• Numero MDL: MFCD00000046
• Codice UNSPSC: 12352103
• ID PubChem: 24855279
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Impiego in reazioni chimiche: reaction type: Grignard Reaction
• Concentrazione: 2.0 M in diethyl ether
• Densità: 0.965 g/mL at 25 °C
• Stringa SMILE: CCCCCC[Mg]Br
• InChI: 1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1; SFXUWNMDTWQSHE-UHFFFAOYSA-M

Descrizione

Descrizione generale

Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.

Applicazioni

Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS05,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H225,H260,H302,H314,H336
• Consigli di prudenza: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Organi bersaglio: Central nervous system
• Rischi supp: EUH019
• Codice della classe di stoccaggio: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): -40.0 °F - closed cup
• Punto d’infiammabilità (°C): -40 °C - closed cup
• Dispositivi di protezione individuale: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter