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Key Documents

241911

Sigma-Aldrich

Tungsten(VI) chloride

≥99.9% trace metals basis

Sinonimo/i:

Tungsten hexachloride

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About This Item

Formula condensata:
WCl6
Numero CAS:
Peso molecolare:
396.56
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.23

Tensione di vapore

43 mmHg ( 215 °C)

Livello qualitativo

Saggio

≥99.9% trace metals basis

Forma fisica

powder

Impiego in reazioni chimiche

reagent type: catalyst
core: tungsten

Impurezze

≤1000.0 ppm Trace Metal Analysis

P. eboll.

347 °C (lit.)

Punto di fusione

275 °C (lit.)

Densità

3.52 g/mL at 25 °C (lit.)

Stringa SMILE

Cl[W](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.W/h6*1H;/q;;;;;;+6/p-6
KPGXUAIFQMJJFB-UHFFFAOYSA-H

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Descrizione generale

Tungsten(VI) chloride is a highly reactive crystalline solid commonly used in the field of catalysis, perovskite solar cells, and light-emitting devices. It is a diamagnetic solid. However, it can be highly corrosive and have strong oxidizing effects.

Applicazioni

Tungsten(VI) chloride can be used:
  • As a starting material to synthesize tungsten nanoparticles and Mo-doped urchin-like W18O49 Nanostructure using the hydrothermal method. The Mo-W18O49 electrocatalyst exhibited excellent electrocatalytic activity toward Hydrogen Evolution Reaction (HER). By doping Mo species into defect-rich W18O49 ultrathin nanowires, it has also been demonstrated to be an excellent candidate for photocatalytic N2 fixation to ammonia.
  • To synthesize crystalline mesoporous WO3 with 11 nm pore size utilizing a high-molecular-weight amphiphilic block copolymer as the structure-directing agent. The materials performed admirably in terms of H2S gas sensing.
  • To fabricate Tungsten disulfide and WS2/reduced graphene oxide (WS2/rGO) nanosheets by hydrothermal synthesis. The WS2/rGO nanosheets showed exceptional electrocatalytic activity for the hydrogen evolution reaction.
  • To produce the WS2-nanoflowers@rGO and nitrogen-doped carbon spheres@WS2 composite as an anode material for enhanced electrode performance in lithium-ion batteries.
  • As a dopant to fabricate TiO2 compact layers for perovskite solar cells with enhanced performance.
  • As a catalyst to prepare self-healing epoxy composites with microcapsules.
  • As a catalyst for transamidation of tertiary alkyl amides.

Pittogrammi

CorrosionExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Articoli

In the last two decades, a new method termed solid-state metathesis (SSM) has been developed to synthesize compounds that are often difficult to produce conventionally.

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