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187054

Sigma-Aldrich

4-Bromobenzyl alcohol

99%

Sinonimo/i:

(4-Bromophenyl)methanol, (p-Bromophenyl)methanol, 1-(p-Bromophenyl)methanol, 1-Bromo-4-(hydroxymethyl)benzene, 4-Hydroxymethyl-1-bromobenzene, p-Bromobenzyl alcohol

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About This Item

Formula condensata:
BrC6H4CH2OH
Numero CAS:
873-75-6
Peso molecolare:
187.03
Beilstein:
1931620
Numero CE:
212-851-7
Numero MDL:
MFCD00004650
Codice UNSPSC:
12352100
ID PubChem:
24851248
NACRES:
NA.22

Saggio

99%

Forma fisica

solid

Punto di fusione

75-77 °C (lit.)

Solubilità

dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow

Gruppo funzionale

bromo

Stringa SMILE

OCc1ccc(Br)cc1

InChI

1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
VEDDBHYQWFOITD-UHFFFAOYSA-N

Informazioni sul gene

human ... ALOX12(239) , ALOX15(246)

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Descrizione generale

4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.

Applicazioni

4-Bromobenzyl alcohol was used in the synthesis of:
  • hydroxyl end functionalized, substituted polyfluorene
  • amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)

Indicazioni di pericolo

H412

Consigli di prudenza

P273 - P501

Classi di pericolo

Aquatic Chronic 3

Codice della classe di stoccaggio

13 - Non Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

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Certificati d'analisi (COA)

Lot/Batch Number
WXBD2150V
WXBC5920V
MKCC8700
S47430V
05706EJ

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