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Documenti fondamentali

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115150

Sigma-Aldrich

Thiophosgene

Sinonimo/i:

Thiocarbonyl chloride

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About This Item

Formula condensata:
CSCl2
Numero CAS:
463-71-8
Peso molecolare:
114.98
Beilstein:
1633495
Numero CE:
207-341-6
Numero MDL:
MFCD00004918
Codice UNSPSC:
12352000
eCl@ss:
38020402
ID PubChem:
24847201
NACRES:
NA.22

Densità del vapore

4 (vs air)

Livello qualitativo

200

Impiego in reazioni chimiche

reaction type: Carbonylations

Indice di rifrazione

n20/D 1.548 (lit.)

P. ebollizione

70-75 °C (lit.)

Densità

1.50 g/mL at 20 °C (lit.)

Gruppo funzionale

chloro

Temperatura di conservazione

2-8°C

Stringa SMILE

ClC(Cl)=S

InChI

1S/CCl2S/c2-1(3)4
ZWZVWGITAAIFPS-UHFFFAOYSA-N

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Applicazioni

Reagent used to prepare a bulky thiourea ligand for palladium-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.

Pittogrammi

Skull and crossbonesCorrosion
GHS06,GHS05

Avvertenze

Danger

Indicazioni di pericolo

H302,H315,H318,H331,H335

Classi di pericolo

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
STBJ7925
STBH8658
STBH9037
STBH9036
STBH8659

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Phosgene solution 15 wt. % in toluene

Sigma-Aldrich

748684

Phosgene solution

Schreiner′s Thiourea Catalyst 95%

Sigma-Aldrich

803863

Schreiner′s Thiourea Catalyst

Trichloromethyl chloroformate ≥97.0% (GC)

Sigma-Aldrich

23261

Trichloromethyl chloroformate

Bis(trichloromethyl) carbonate purum, ≥99.0% (AT)

Sigma-Aldrich

15217

Bis(trichloromethyl) carbonate

W Kedzierski et al.
The Journal of chemical physics, 120(19), 9087-9089 (2004-07-23)
A special xenon matrix detector has been used to study the production of S(1S) following controlled electron impact on thiophosgene (Cl2CS) targets over an electron energy range from threshold to 400 eV. Time-of-flight spectroscopy has been used to measure S(1S)
Christof Jung et al.
The journal of physical chemistry. A, 110(16), 5317-5325 (2006-04-21)
The dispersed fluorescence spectrum of the ground electronic state of thiophosgene, SCCl2, is analyzed in a very complex region of vibrational excitation, 7000-9000 cm(-1). The final result is that most of the inferred excited vibrational levels are assigned in terms
Cheng Li et al.
Colloids and surfaces. B, Biointerfaces, 171, 159-166 (2018-07-22)
Dual mode imaging technology is widely developed to achieve the early-stage precision cancer diagnosis. Here we designed a dual-modal magnetic resonance/near infrared fluorescence optical imaging contrast agent (GdF-SS-NIR783) with the fluorescence activatable and safer gadofullerene. The nanoprobes were fabricated by
Youlia Hagooly et al.
The Journal of organic chemistry, 73(17), 6780-6783 (2008-08-13)
A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination step is complete
T A Lewis et al.
Journal of bacteriology, 177(8), 2204-2208 (1995-04-01)
Pseudomonas sp. strain KC transforms carbon tetrachloride into carbon dioxide and nonvolatile products, without chloroform as an intermediate. To define the pathway for hydrolysis, nonvolatile products were analyzed. Condensation products containing the carbon atom of carbon tetrachloride as carbonyl and
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