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103764

Sigma-Aldrich

Pentafluorobenzenesulfonyl chloride

99%

Sinonimo/i:

2,3,4,5,6-Pentafluorophenylsulfonyl chloride, Perfluorobenzenesulfonyl chloride

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About This Item

Formula condensata:
C6F5SO2Cl
Numero CAS:
832-53-1
Peso molecolare:
266.57
Beilstein:
2142325
Numero CE:
212-620-0
Numero MDL:
MFCD00007427
Codice UNSPSC:
12352100
ID PubChem:
24846621
NACRES:
NA.22

Saggio

99%

Stato

solid

Indice di rifrazione

n20/D 1.479 (lit.)

P. ebollizione

210-211 °C (lit.)

Densità

1.796 g/mL at 25 °C (lit.)

Gruppo funzionale

chloro
fluoro

Stringa SMILE

Fc1c(F)c(F)c(c(F)c1F)S(Cl)(=O)=O

InChI

1S/C6ClF5O2S/c7-15(13,14)6-4(11)2(9)1(8)3(10)5(6)12
UOJCTEGNHXRPKO-UHFFFAOYSA-N

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Descrizione generale

Pentafluorobenzenesulfonyl chloride reacts with benzene and thiophene derivatives in the presence of a ruthenium (II) catalyst to form corresponding perfluorophenylated compounds.

Applicazioni

Pentafluorobenzenesulfonyl chloride was used as derivatizing reagent for simultaneous determination of fluoxetine and p-trifluoromethylphenol, an O-dealkylated metabolite of fluoxetine in human liver microsomes. Pentafluorobenzenesulfonyl chloride was used for electrophore labeling of small tyrosyl peptides for their analysis by gas chromatography with electron-capture detection.

Azioni biochim/fisiol

Pentafluorobenzenesulfonyl chloride is derivatizing reagent for amphetamine in determination of amphetamine in human plasma samples using gas chromatography with electron-capture detectio.

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H314

Classi di pericolo

Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

194.0 °F - closed cup

Punto d’infiammabilità (°C)

90 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
BCCB7949
BCBW5597
BCBT3555
BCBS2911V
BCBR2167V

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Sigma-Aldrich

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Sigma-Aldrich

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4-Methoxybenzenesulfonyl chloride 99%

Sigma-Aldrich

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4-Methoxybenzenesulfonyl chloride

G B Baker et al.
Journal of chromatography, 381(2), 211-217 (1986-09-05)
A gas chromatographic procedure is described for the analysis of beta-phenylethylamine (PEA) in tissues and body fluids. The method involves the use of pentafluorobenzenesulfonyl chloride for extraction and derivatization of PEA. This is followed by separation and analysis of the
Perfluorophenylation of aromatic and heteroaromatic compounds with pentafluorobenzenesulfonyl chloride catalyzed by a ruthenium (II) phosphine complex.
Kamigata N, et al.
Journal of Fluorine Chemistry, 87(1), 91-95 (1998)
Pentafluorobenzenesulfonyl chloride as a sensitive reagent for the rapid gas chromatographic analysis of tranylcypromine in tissues and body fluids.
T S Rao et al.
Biochemical pharmacology, 35(12), 1925-1928 (1986-06-15)
Pentafluorobenzenesulfonyl chloride: a new electrophoric derivatizing reagent with application to tyrosyl peptide determination by gas chromatography with electron capture detection.
A Sentissi et al.
Analytical chemistry, 56(13), 2512-2517 (1984-11-01)
S J Asghar et al.
Journal of pharmacological and toxicological methods, 46(2), 111-115 (2002-12-17)
Acute administration of (+)-amphetamine has been used as a model for mania in humans since it mimics the physiological, biochemical, and cognitive effects seen in mania. A rapid and sensitive method for the determination of amphetamine in human plasma samples
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