221457
N,N-Dimethylhydroxylamine hydrochloride
99%
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About This Item
Formule linéaire :
(CH3)2NOH · HCl
Numéro CAS:
Poids moléculaire :
97.54
Beilstein:
3905683
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352100
ID de substance PubChem :
Nomenclature NACRES :
NA.22
Produits recommandés
Essai
99%
Forme
solid
Pf
107-109 °C (lit.)
Groupe fonctionnel
amine
Chaîne SMILES
Cl[H].CN(C)O
InChI
1S/C2H7NO.ClH/c1-3(2)4;/h4H,1-2H3;1H
Clé InChI
HWWVAHCWJLGKLW-UHFFFAOYSA-N
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Description générale
N,N-Dimethylhydroxylamine hydrochloride is an organic compound often used as an organocatalyst to increase Morita-Baylis-Hillman reaction rate by reducing the activation energy of the rate-limiting aldol step.
Application
N,N-Dimethylhydroxylamine hydrochloride was used in the synthesis of 4,4-dimethyl-2,5,5-triphenyl-l.3-dioxa-4-azonia-2-bora-5-boratacyclopentane. It was also used as a polymer-chain terminator.
Mention d'avertissement
Warning
Mentions de danger
Conseils de prudence
Classification des risques
Eye Irrit. 2 - Skin Irrit. 2
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
dust mask type N95 (US), Eyeshields, Gloves
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Les clients ont également consulté
Structural studies of organoboron compounds. XVI. Preparation and crystal and molecular structures of 4, 4-dimethyl-2, 5, 5-triphenyl-1, 3-dioxa-4-azonia-2-bora-5-boratacyclopentane and 4, 4, 5, 5-tetramethyl-2, 2-diphenyl-1, 3-dioxa-4-azonia-2-boratacyclopentane.
Canadian Journal of Chemistry, 62(5), 838-844 (1984)
Hana Popelkova et al.
Photosynthesis research, 110(2), 111-121 (2011-11-02)
The photosystem II (PSII) manganese-stabilizing protein (PsbO) is known to be the essential PSII extrinsic subunit for stabilization and retention of the Mn and Cl(-) cofactors in the oxygen evolving complex (OEC) of PSII, but its function relative to Ca(2+)
A R Tunoori et al.
Organic letters, 2(25), 4091-4093 (2000-12-12)
[structure] The reagent [bis(2-methoxyethyl)amino]sulfur trifluoride (Deoxo-Fluor reagent) converts carboxylic acids to the corresponding acid fluorides, which then react with N,N-dimethylhydroxylamine to give the corresponding Weinreb amides in high yields. The reaction proceeds without racemization when optically active acids are used
K Stolze et al.
Free radical research communications, 8(2), 123-131 (1990-01-01)
Nitroxide radicals have been detected in the methemoglobin formation reaction between oxyhemoglobin and the substituted hydroxylamine compounds, N-methylhydroxylamine and N,N-dimethylhydroxylamine, by ESR spectroscopy. The stability of these nitroxide radicals was considerably higher than that of the NH2O. radical derived from
J Taira et al.
Biochimica et biophysica acta, 1336(3), 502-508 (1997-11-21)
Hydroxylamine (HA), which is a natural product of mammalian cells, has been shown to possess vasodilatory properties in several model systems. In this study, HA and methyl-substituted hydroxylamines, N-methylhydroxylamine (NMHA) and N,N-dimethylhydroxylamine (NDMHA), have been tested for their ability to
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